1. 1.Whitmire, K. H.; Schipper, D. E., In pursuit of advanced materials from single-source precursors based on metal carbonyls. Dalton Trans. 2019, 48, 2248-2262, DOI: 10.1039/c8dt03406k.

  2. 2. Whitmire, K. H.; Schipper, D. E.; Zhao, Z.; Leitner, A.; Bao, J. Thin films of transition metal phosphides coated on a semiconductor core from organometallic precursors for oxygen evolution and hydrogen evolution catalysis. WO2018175594A1, 2018.

  3. 3.Whitmire, K. H., Transition metal complexes of the naked pnictide elements. Coord. Chem. Rev. 2018, 376, 114-195, DOI: 10.1016/j.ccr.2018.06.012.

  4. 4.Schipper, D. E.; Zhao, Z.; Leitner, A. P.; Donaldson, S. L.; Kumar, A.; Qin, F.; Wang, Z.; Bao, J.; Thirumalai, H.; Grabow, L. C.; Whitmire, K., H., Effects of Catalyst Phase on the Hydrogen Evolution Reaction of Water Splitting: Preparation of Phase-Pure Films of FeP, Fe2P, and Fe3P and their Relative Catalytic Activities. Chem. Mater. 2018, 3588–3598, DOI: 10.1021/acs.chemmater.8b01624.

  5. 5.Chen, J.-H.; Whitmire, K. H., A structural survey of the binary transition metal phosphides and arsenides of the d-block elements. Coord. Chem. Rev. 2018, 355, 271-327, DOI: 10.1016/j.ccr.2017.08.029

  6. 6.Zhao, Z.; Schipper, D. E.; Leitner, A. P.; Thirumalai, H.; Chen, J.-H.; Xie, L.; Qin, F.; Alam, M. K.; Grabow, L. C.; Chen, S.; Wang, D.; Ren, Z.; Wang, Z.; Whitmire, K. H.; Bao, J., Bifunctional metal phosphide FeMnP films from single source metal organic chemical vapor deposition for efficient overall water splitting. Nano Energy 2017, 39, 444-453, DOI: 10.1016/j.nanoen.2017.07.027.

  7. 7.Schipper, D. E.; Zhao, Z.; Leitner, A. P.; Xie, L.; Qin, F.; Alam, M. K.; Chen, S.; Wang, D.; Ren, Z.; Wang, Z.; Bao, J.; Whitmire, K. H., A TiO2/FeMnP Core/Shell Nanorod Array Photoanode for Efficient Photoelectrochemical Oxygen Evolution. ACS Nano 2017, 11, 4051-4059, DOI: 10.1021/acsnano.7b00704.

  8. 8.Schipper, D. E.; Chen, J.-H.; Whitmire, K. H., Iron carbonyl clusters with ECl2 units (E = P, As). J. Organomet. Chem. 2017, 849-850, 279-285, DOI: 10.1016/j.jorganchem.2017.03.008.

  9. 9.Moghaddam, S. E.; Hejazi, V.; Hwang, S. H.; Sreenivasan, S.; Miller, J.; Shi, B.; Zhao, S.; Rusakova, I.; Alizadeh, A. R.; Whitmire, K. H.; Shahsavari, R., Morphogenesis of cement hydrate. J. Mater. Chem. A 2017, 5, 3798-3811, DOI: 10.1039/C6TA09389B.

  10. 10. Margulieux, K. R.; Sun, C.; Kihara, M. T.; Colson, A. C.; Zakharov, L. N.; Whitmire, K. H.; Holland, A. W.; Pak, J. J., Synthesis and Characterization of Bimetallic Single-Source Precursors (Ph3P)2M(μ-SEt)2E(SEt)2 for MES2 Chalcopyrite Materials (M = Cu, Ag and E = In, Ga, Al). Eur. J. Inorg. Chem. 2017, 2017, 2068-2077, DOI: 10.1002/ejic.201700115.

  11. 11.Leitner, A. P.; Schipper, D. E.; Chen, J.-H.; Colson, A. C.; Rusakova, I.; Rai, B. K.; Morosan, E.; Whitmire, K. H., Synthesis of Hexagonal FeMnP Thin Films from a Single-Source Molecular Precursor. Chem. - Eur. J. 2017, 23, 5565-5572, DOI: 10.1002/chem.201700203.

  12. 12.Kelly, A. T.; Filgueira, C. S.; Schipper, D. E.; Halas, N. J.; Whitmire, K. H., Gold coated iron phosphide core-shell structures. RSC Adv. 2017, 7, 25848-25854, DOI: 10.1039/C7RA01195D.

  13. 13.Hernandez-Rivera, M.; Kumar, I.; Cho, S. Y.; Cheong, B. Y.; Pulikkathara, M. X.; Moghaddam, S. E.; Whitmire, K. H.; Wilson, L. J., High-Performance Hybrid Bismuth-Carbon Nanotube Based Contrast Agent for X-ray CT Imaging. ACS Appl. Mater. Interfaces 2017, 9, 5709-5716, DOI: 10.1021/acsami.6b12768.

  14. 14.Andleeb, S.; Donaldson, S. L.; Schipper, D. E.; Loera Fernandez, I. I.; ud Din, I.; Whitmire, K. H., Anionic Bismuth Oxido Clusters with Pendant Silver Cations: Synthesis and Structures of {[Bi4(μ3-O)2(TFA)9Ag(tol)2]2} and {Bi4(μ3-O)2(TFA)10(AgPPh3)2}n. Eur. J. Inorg. Chem. 2017, 2017, 1457-1463, DOI: 10.1002/ejic.201601430.

  15. 15.Schipper, D. E.; Young, B. E.; Whitmire, K. H., Transformations in Transition-Metal Carbonyls Containing Arsenic: Exploring the Chemistry of [Et4N]2[HAs{Fe(CO)4}3] in the Search for Single-Source Precursors for Advanced Metal Pnictide Materials. Organometallics 2016, 35, 471-483, DOI: 10.1021/acs.organomet.5b00906.

  16. 16.Schipper, D. E.; Ikhlef, D.; Khalal, S.; Saillard, J.-Y.; Whitmire, K. H., New Main-Group-Element-Rich nido-Octahedral Cluster System: Synthesis and Characterization of [Et4N][Fe2(CO)6(μ3-As){μ3-EFe(CO)4}2]. Inorg. Chem. 2016, 55, 6679-6684, DOI: 10.1021/acs.inorgchem.6b00921.

  17. 17.Loera Fernandez, I. I.; Donaldson, S. L.; Schipper, D. E.; Andleeb, S.; Whitmire, K. H., Anionic Bismuth-Oxido Carboxylate Clusters with Transition Metal Countercations. Inorg. Chem. 2016, 55, 11560-11569, DOI: 10.1021/acs.inorgchem.6b02092.

  18. 18.Leitner, A. P.; Chen, J.-H.; Schipper, D. E.; Whitmire, K. H., Thin Films of (Fe1-xCox)3P and Fe3(P1-xTex) from the Co-Decomposition of Organometallic Precursors by MOCVD. Chem. Mater 2016, 28, 7066-71, DOI: 10.1021/acs.chemmater.6b02943.

  19. 19.Shahsavari, R.; Ebrahimpourmoghaddam, S.; Whitmire, K. H. Shape-controlled calcium silicate hydrate cement synthesis and self-assembly. WO2015171745A1, 2015.

  20. 20.McClain, M. J.; Schlather, A. E.; Ringe, E.; King, N. S.; Liu, L.; Manjavacas, A.; Knight, M. W.; Kumar, I.; Whitmire, K. H.; Everitt, H. O.; Nordlander, P.; Halas, N. J., Aluminum Nanocrystals. Nano Lett. 2015, 15, 2751-2755, DOI: 10.1021/acs.nanolett.5b00614.

  21. 21.Kumar, I.; Bhattacharya, P.; Whitmire, K. H., Structural diversity in phenyl bismuth(III) bis(carboxylate) complexes. J. Organomet. Chem. 2015, 794, 153-167, DOI: 10.1016/j.jorganchem.2015.06.023.

  22. 22.Kumar, I.; Andrews, P.; Whitmire, K. H., The Unexpected Isolation of Bismuth Tris(carboxylate) Hydrates: Syntheses and Structures of [Bi(Hsal)3(H2O)] and [Bi(Hanth)3(H2O)] (H2sal = 2-OH-C6H4CO2H, Hanth = 2-NH2-C6H4CO2H). Eur. J. Inorg. Chem. 2015, 2015, 605-608, DOI: 10.1002/ejic.201403019.

  23. 23.Davidovich, R. L.; Marinin, D. V.; Stavila, V.; Whitmire, K. H., Structural chemistry of fluoride and oxofluoride complexes of titanium(IV). Coord. Chem. Rev. 2015, 299, 61-82, DOI: 10.1016/j.ccr.2015.04.002.

  24. 24.Kumar, I.; Bhattacharya, P.; Whitmire, K. H., Facile One-Pot Synthesis of Triphenylbismuth(V) Bis(carboxylate) Complexes. Organometallics 2014, 33, 2906-2909, DOI: 10.1021/om500337z.

  25. 25.Ching, S.; Prieto-Centurion, D.; Kiappes, J. L., Jr.; Whitmire, K. H., 41. Bis[bis(triphenylphosphoranylidene)-ammonium] undecacarbonyltriferrate(2-). Inorg. Synth. 2014, 36, 223-226, DOI: 10.1002/9781118744994.ch41.

  26. 26.Bulimestru, I.; Shova, S.; Popa, N.; Roussel, P.; Capet, F.; Vannier, R.-N.; Djelal, N.; Burylo, L.; Wignacourt, J.-P.; Gulea, A.; Whitmire, K. H., Aminopolycarboxylate Bismuth(III)-Based Heterometallic Compounds as Single-Source Molecular Precursors for Bi4V2O11 and Bi2CuO4 Mixed Oxides. Chem. Mater. 2014, 26, 6092-6103, DOI: 10.1021/cm502009y

  27. 27.Boyd, T. D.; Kumar, I.; Wagner, E. E.; Whitmire, K. H., Synthesis and structural studies of the simplest bismuth(III) oxo-salicylate complex: [Bi4(μ3-O)2(HO-2-C6H4CO2)8]·2Solv (Solv = MeCN or MeNO2). Chem. Commun. 2014, 50, 3556-3559, DOI: 10.1039/c4cc00056k

  28. 28.Whitmire, K. H., Bismuth: Inorganic Chemistry. In Encyclopedia of Inorganic and Bioinorganic Chemistry, John Wiley & Sons Ltd.: 2013; pp 1-32.

  29. 29.Walsh, S. R.; Rusakova, I.; Whitmire, K., H., Rock Salt vs. Wurtzite Phases of Co1-xMnxO: Control of Crystal Lattice and Morphology at the Nanoscale. CrystEngComm 2013, 15, 775 - 784, DOI: 10.1039/c2ce26440d.

  30. 30.Ould-Ely, T.; Prieto-Centurion, D.; Rusakova, I.; Whitmire, K. H., Wet chemical synthesis and characterization of polypodal In2O3 nanoparticles. CrystEngComm 2013, 15, 6918-6922, DOI: 10.1039/c3ce41264d.

  31. 31.Davidovich, R. L.; Marinin, D. V.; Stavila, V.; Whitmire, K. H., Stereochemistry of fluoride and mixed-ligand fluoride complexes of zirconium and hafnium. Coord. Chem. Rev. 2013, 257, 3074-3088, DOI: 10.1016/j.ccr.2013.06.016.

  32. 32.Colson, A. C.; Chen, C.-W.; Morosan, E.; Whitmire, K. H., Synthesis of Phase-Pure Ferromagnetic Fe3P Films from Single-Source Molecular Precursors. Adv. Funct. Mater. 2012, 22, 1850-1855, DOI: 10.1002/adfm.201102386.

  33. 33.Whitmire, K. H.; Caudell, J. B., First Row Transition Metal Phosphides. In Encyclopedia of Inorganic and Bioinorganic Chemistry, John Wiley & Sons, Ltd: online, 2011; pp 1-18.

  34. 34.Whitmire, K. H., Bismuth: organometallic chemistry. In Encyclopedia for Inorganic and Bioinorganic Chemistry, John Wiley & Sons Ltd.: 2011; pp 1-16.

  35. 35.Stavila, V.; Whitmire, K. H., Hexaaquacobalt(II) and hexaaquanickel(II) pyridine-2,6-dicarboxylatobismuth(III) dihydrates. Acta Cryst. 2011, C67, m65-m68, DOI: 10.1107/S0108270110053497.

  36. 36.Mandal, T.; Piburn, G.; Stavila, V.; Rusakova, I.; Ould-Ely, T.; Colson, A. C.; Whitmire, K. H., New Mixed Ligand Single-Source Precursors for PbS Nanoparticles and Their Solvothermal Decomposition to Anisotropic Nano- And Microstructures. Chem. Mater. 2011, 23, 4158-4169, DOI: 10.1021/cm201064c.

  37. 37.Colson, A. C.; Whitmire, K. H., Synthesis of Fe2-xMnxP Nanoparticles from Single-Source Molecular Precursors. Chem. Mater. 2011, 23, 3731-3739, DOI: 10.1021/cm201435b.

  38. 38.Whitmire, K. H., Molecular donuts and donut holes. Science 2010, 327, 38-39, DOI: 10.1126/science.1184533.

  39. 39.Stavila, V.; Whitmire, K. H., (N,N-dimethylformamide-κ,O)bis(3-hydroxypicolinate-κ2N,O)phenylbismuth(III). Acta Crystallogr., Sect. E Struct. Rep. Online 2010, E66, m1547-m1548, DOI: 10.1107/s1600536810044235.

  40. 40.Davidovich, R. L.; Stavila, V.; Whitmire, K. H., Stereochemistry of lead(II) complexes containing sulfur and selenium donor atom ligands. Coord. Chem. Rev. 2010, 254, 2193-2226, DOI: 10.1016/j.ccr.2010.05.013.

  41. 41.Colson, A. C.; Whitmire, K. H., Synthesis, Characterization, and Reactivity of the Heterometallic Dinuclear μ-PH2 and μ-PPhH Complexes FeMn(CO)8(μ-PH2) and FeMn(CO)8(μ-PPhH). Organometallics 2010, 29, 4611-4618, DOI: 10.1021/om100736m.

  42. 42.Bochmann, M.; Brookhart, M.; Gladysz, J. A.; Lichtenberger, D. L.; Liebeskind, L. S.; Marks, T. J.; Schrock, R. R.; Sweigart, D. A.; Whitmire, K. H., Dedication to the Special Volume for Dietmar Seyferth. Organometallics 2010, 29, 4647, DOI: 10.1021/om100975m.

  43. 43.Stavila, V.; Whitmire, K. H.; Rusakova, I., Synthesis of Bi2S3 Nanostructures from Bismuth(III) Thiourea and Thiosemicarbazide Complexes. Chem. Mater. 2009, 21, 5456-5465, DOI: DOI:10.1021/cm902229x.

  44. 44.Stavila, V.; Thurston, J. H.; Whitmire, K. H., Selective Arylation Reactions of Bismuth-Transition Metal Salicylate Complexes. Inorg. Chem. 2009, 48, 6945-6951, DOI: 10.1021/ic9010357.

  45. 45.Mandal, T.; Stavila, V.; Rusakova, I.; Ghosh, S.; Whitmire, K. H., Molecular Precursors for CdS Nanoparticles: Synthesis and Characterization of Carboxylate-Thiourea or -Thiosemicarbazide Cadmium Complexes and Their Decomposition. Chem. Mater. 2009, 21, 5617-5626, DOI: DOI:10.1021/cm902230u.

  46. 46.Levin, C. S.; Hofmann, C.; Ali, T. A.; Kelly, A. T.; Morosan, E.; Nordlander, P.; Whitmire, K. H.; Halas, N. J., Magnetic-Plasmonic Core-Shell Nanoparticles. ACS Nano 2009, 3, 1379-1388, DOI: DOI:10.1021/nn900118a.

  47. 47.Hofmann, C.; Thurston, J. H.; Hartman, K. B.; Alemany, L. B.; Whitmire, K. H., New polyoxomolybdenum coordination compounds: Synthesis and characterization of mixed-valent Mo6O13(Hsal)2(sal)2(acac)2 and homovalent Mo4O10(acac)4 (Hsal- = 2-HO-C6H4CO2-, sal2- = 2-O-C6H4CO22-). Inorg. Chim. Acta 2009, 362, 1665-1671, DOI: 10.1016/j.ica.2008.08.029.

  48. 48.Davidovich, R. L.; Stavila, V.; Marinin, D. V.; Voit, E. I.; Whitmire, K. H., Stereochemistry of lead(II) complexes with oxygen donor ligands. Coord. Chem. Rev. 2009, 253, 1316-1352, DOI: 10.1016/j.ccr.2008.09.003.

  49. 49.Machnikova, E.; Whitmire, K. H.; Hackerman, N., Corrosion inhibition of carbon steel in hydrochloric acid by furan derivatives. Electrochim. Acta 2008, 53, 6024-6032, DOI: 10.1016/j.electacta.2008.03.021.

  50. 50.Hofmann, C.; Rusakova, I.; Ould-Ely, T.; Prieto-Centurion, D.; Hartman, K. B.; Kelly, A. T.; Luttge, A.; Whitmire, K. H., Shape control of new FexO-Fe3O4 and Fe1-yMnyO-Fe3-zMnzO4 nanostructures. Adv. Funct. Mater. 2008, 18, 1661-1667, DOI: 10.1002/adfm.200701119.

  51. 51.Zhao, B.-J.; Shine, H. J.; Marx, J. N.; Hofmann, C.; Whitmire, K. H., Addition of the Phenoxathiin Cation Radical to Alkenes and Nonconjugated Dienes. Formation of (E)- and (Z)-(10-Phenoxathiiniumyl)alkenes and (E)- and (Z)-(10-Phenoxathiiniumyl)dienes on Basic Alumina. J. Org. Chem. 2007, 72, 6154-6161, DOI: 10.1021/jo070898b.

  52. 52.Whitmire, K., H.; Kelly, A. T.; Hofmann, C., Mononuclear Iron Carbonyls without Hydrocarbon Ligands. In Comprehensive Organometallic Chemistry III, Crabtree, R. H.; Mingos, D. M. P., Eds. Elsevier: Oxford, 2007; Vol. 6, pp 1 - 76.

  53. 53.Whitmire, K., H., d-Block Complexes of Aluminum, Gallium, Indium, and Thallium. In Comprehensive Organometallic Chemistry III, Crabtree, R. H.; Mingos, D. M. P., Eds. Elsevier: Oxford, 2007; Vol. 3, pp 343 - 408.

  54. 54.Stavila, V.; Thurston, J. H.; Prieto-Centurion, D.; Whitmire, K. H., A new methodology for synthesis of aryl bismuth compounds: arylation of bismuth(III) carboxylates by sodium tetraarylborate salts. Organometallics 2007, 26, 6864-6866, DOI: 10.1021/om7009667.

  55. 55.Stavila, V.; Fettinger, J. C.; Whitmire, K. H., Synthesis and Characterization of New Phenylbis(salicylato)bismuth(III) Complexes. Organometallics 2007, 26, 3321-3328, DOI: 10.1021/om070115c.

  56. 56.Shamsuddin, S.; Ali, M. S.; Whitmire, K. H.; Khokhar, A. R., Synthesis characterization and X-ray crystal structures of cis-1,4-diaminocyclohexane-platinum(II) nucleobase adducts. Polyhedron 2007, 26, 637-644, DOI: 10.1016/j.poly.2006.08.033.

  57. 57.Rusakova, I.; Ould-Ely, T.; Hofmann, C.; Prieto-Centurion, D.; Levin, C. S.; Halas, N. J.; Luettge, A.; Whitmire, K. H., Nanoparticle Shape Conservation in the Conversion of MnO Nanocrosses into Mn3O4. Chem. Mater. 2007, 19, 1369-1375, DOI: 10.1021/cm062649u.

  58. 58.Kelly, A. T.; Rusakova, I.; Ould-Ely, T.; Hofmann, C.; Luettge, A.; Whitmire, K. H., Iron Phosphide Nanostructures Produced from a Single-Source Organometallic Precursor: Nanorods, Bundles, Crosses, and Spherulites. Nano Letters 2007, 7, 2920-2925, DOI: 10.1021/nl0713225.

  59. 59.Zhao, B.-J.; Shine, H.; Marx, J.; Kelly, A.; Hofmann, C.; Whitmire, K., Addition of thianthrene cation radical to non-conjugated dienes-Part I: Addition to one double bond. J. Sulfur Chem. 2006, 27, 127-138, DOI: 10.1080/17415990600578574.

  60. 60.Zhao, B.-J.; Shine, H.; Marx, J.; Kelly, A.; Hofmann, C.; Ould-Ely, T.; Whitmire, K., Addition of thianthrene cation radical to non-conjugated dienes-Part II: Addition to two double bonds. J. Sulfur Chem. 2006, 27, 139-147, DOI: 10.1080/17415990600578467.

  61. 61.Stavila, V.; Davidovich, R. L.; Gulea, A.; Whitmire, K. H., Bismuth(III) complexes with aminopolycarboxylate and polyaminopolycarboxylate ligands: Chemistry and structure. Coord. Chem. Rev. 2006, 250, 2782-2810, DOI: 10.1016/j.ccr.2006.02.032.

  62. 62.Ould-Ely, T.; Prieto-Centurion, D.; Kumar, A.; Guo, W.; Knowles, W. V.; Asokan, S.; Wong, M. S.; Rusakova, I.; Luettge, A.; Whitmire, K. H., Manganese(II) Oxide Nanohexapods: Insight into Controlling the Form of Nanocrystals. Chem. Mater. 2006, 18, 1821-1829, DOI: 10.1021/cm052492q.

  63. 63.Ali, M. S.; Longoria, E.; Ould-Ely, T.; Whitmire, K. H.; Khokhar, A. R., Homopiperazine Pt(II) adducts with DNA bases and nucleosides: Crystal structure of [PtII(homopiperazine)(9-ethylguanine)2](NO3)2. Polyhedron 2006, 25, 2065-2071, DOI: 10.1016/j.poly.2006.01.003.

  64. 64.Whitmire, K. H., Bismuth: Inorganic Chemistry. In Encyclopedia of Inorganic Chemistry, 2nd ed.; King, R. B., Ed. Wiley Interscience: New York, NY, 2005; Vol. 1, pp 404-425.

  65. 65.Whitmire, K. H., Bismuth: Organometallic Chemistry. In Encyclopedia of Inorganic Chemistry, 2nd ed.; King, R. B., Ed. Wiley Interscience: New York, NY, 2005; Vol. 1, pp 425-440.

  66. 66.Shine, H. J.; Rangappa, P.; Marx, J. N.; Shelly, D. C.; Ould-Ely, T.; Whitmire, K. H., Adducts of Thianthrene- and Phenoxathiin Cation Radical Salts with Symmetrical Alkynes. Structure and Formation of Cumulenes on Alumina Leading to a-Diketones, a-Hydroxyalkynes, and a-Acetamidoalkynes. J. Org. Chem. 2005, 70, 3877-3883, DOI: 10.1021/jo050198b.

  67. 67.Seyferth, D.; Marks, T. J.; Liebeskind, L. S.; Sweigart, D. A.; Whitmire, K. H., A Great Day for Organometallic Chemistry. Organometallics 2005, 24, 6073, DOI: 10.1021/om0508942.

  68. 68.Rangappa, P.; Shine, H. J.; Marx, J. N.; Ould-Ely, T.; Kelly, A. T.; Whitmire, K. H., Adducts of Thianthrene- and Phenoxathiin Cation Radical Tetrafluoroborates to 1-Alkynes. Structures and Formation of 1-(5-Thianthreniumyl)- and 1-(10-Phenoxathiiniumyl)alkynes on Alumina Leading to a-Ketoylides and a-Ketols. J. Org. Chem. 2005, 70, 9764-9770, DOI: 10.1021/jo051317q.

  69. 69.Ould-Ely, T.; Thurston, J. H.; Whitmire, K. H., Heterobimetallic bismuth-transition metal coordination complexes as single-source molecular precursors for the formation of advanced oxide materials. Comptes Rend. Chim. 2005, 8, 1906-1921, DOI: 10.1016/j.crci.2005.04.005.

  70. 70.Ould-Ely, T.; Thurston, J. H.; Kumar, A.; Respaud, M.; Guo, W.; Weidenthaler, C.; Whitmire, K. H., Wet-Chemistry Synthesis of Nickel-Bismuth Bimetallic Nanoparticles and Nanowires. Chem. Mater. 2005, 17, 4750-4754, DOI: 10.1021/cm049678u.

  71. 71.Escovar, R. M.; Thurston, J. H.; Ould-Ely, T.; Kumar, A.; Whitmire, K. H., Synthesis and characterization of new mono-, di-, and trinuclear copper(II) triethanolamine-carboxylate complexes. Z. Anorg. Allg. Chem. 2005, 631, 2867-2876, DOI: 10.1002/zaac.200500204.

  72. 72.Ali, M. S.; Ali Khan, S. R.; Ojima, H.; Guzman, I. Y.; Whitmire, K. H.; Siddik, Z. H.; Khokhar, A. R., Model platinum nucleobase and nucleoside complexes and antitumor activity: X-ray crystal structure of [PtIV(trans-1R,2R-diaminocyclohexane)trans(acetate)2(9-ethylguanine)Cl]NO3.H2O. J. Inorg. Biochem. 2005, 99, 795-804, DOI: 10.1016/j.jinorgbio.2004.12.015.

  73. 73.Thurston, J., H.; Trahan, D.; Ould-Ely, T.; Whitmire Kenton, H., Toward a general strategy for the synthesis of heterobimetallic coordination complexes for use as precursors to metal oxide materials: synthesis, characterization, and thermal decomposition of Bi2(Hsal)6.M(acac)3 (M = Al, Co, V, Fe, Cr). Inorg. Chem. 2004, 43, 3299-305, DOI: 10.1021/ic035284d.

  74. 74.Thurston, J., H.; Tang, C., G. Z.; Trahan, D., W.; Whitmire, K., H., Toward rational control of metal stoichiometry in heterobimetallic coordination complexes: synthesis and characterization of Pb(Hsal)2{Cu(salen*)}2, [Pb(NO3){Cu(salen*)}2](NO3), Pb(OAc)2(Cu(salen*)), and [Pb(OAc)(Ni(salen*))2](OAc). Inorg. Chem. 2004, 43, 2708-13, DOI: 10.1021/ic035427w.

  75. 75.Thurston, J., H.; Kumar, A.; Hofmann, C.; Whitmire, K., H., Heterobimetallic Bi(III)-Ti(IV) coordination complexes: synthesis and solid-state structures of BiTi4(sal)6(μ-OiPr)3(OiPr)4, and the cyclic isomers Bi4Ti4(sal)10(μ-OiPr)4(OiPr)4 and Bi8Ti8(sal)20(μ-OiPr)8(OiPr)8. Inorg. Chem. 2004, 43, 8427-36, DOI: 10.1021/ic049061e.

  76. 76.Shine, H. J.; Zhao, B.-J.; Marx, J. N.; Ould-Ely, T.; Whitmire, K. H., Decomposition of Alkene Adducts of Thianthrene Cation Radical in Nitrile Solvents. Formation of Alkyl-2-oxazolines and a New Class of Four-Component Products: 5-[(1-Alkoxyalkylidene)ammonio]alkylthianthrenium Diperchlorates. J. Org. Chem. 2004, 69, 9255-9261, DOI: 10.1021/jo0402125.

  77. 77.Umezawa-Vizzini, K.; Guzman-Jimenez, I. Y.; Whitmire, K. H.; Lee, T. R., Synthesis, Characterization, and Thermal Stability of (η6:η1-C6H5CH2CH2PR2)Ru(CH3)2 (R = Cy, Ph, Et). Organometallics 2003, 22, 3059-3065, DOI: 10.1021/om0300070.

  78. 78.Thurston, J. H.; Whitmire, K. H., Molecular Precursors for Ferroelectric Materials: Synthesis and Characterization of Bi2M2(μ-O)(sal)4(Hsal)4(OEt)2 and BiM4(μ-O)4(sal)4(Hsal)3(OiPr)4 (sal = O2CC6H4O, Hsal = O2CC6H4OH) (M = Nb, Ta). Inorg. Chem. 2003, 42, 2014-2023, DOI: 10.1021/ic026108s.

  79. 79.Thurston, J. H.; Ould-Ely, T.; Trahan, D.; Whitmire, K. H., Nanostructured Bimetallic Oxide Ion-Conducting Ceramics from Single-Source Molecular Precursors. Chem. Mater. 2003, 15, 4407-4416, DOI: 10.1021/cm0342851.

  80. 80.Shine, H. J.; Zhao, B.; Qian, D.-Q.; Marx, J. N.; Guzman-Jimenez, I. Y.; Thurston, J. H.; Ould-Ely, T.; Whitmire, K. H., Adducts of Phenoxathiin and Thianthrene Cation Radicals with Alkenes and Cycloalkenes. J. Org. Chem. 2003, 68, 8910-8917, DOI: 10.1021/jo030173h.

  81. 81.Qian, D.-Q.; Shine, H. J.; Thurston, J. H.; Whitmire, K. H., Nucleophilic reactions of 5-(aryl)thianthrenium bromides with sodium aryloxides. J. Phys. Org. Chem. 2003, 16, 142-147, DOI: 10.1002/poc.585.

  82. 82.Mukhopadhyay, U.; Thurston, J.; Whitmire, K. H.; Siddik, Z. H.; Khokhar, A. R., Preparation, characterization, and antitumor activity of new cisplatin analogues with 1-methyl-4-(methylamino)piperidine: Crystal structure of [PtII(1-methyl-4-(methylamino) piperidine)(oxalate)]. J. Inorg. Biochem. 2003, 94, 179-185, DOI: 10.1016/S0162-0134(02)00614-1.

  83. 83.Guzman-Jimenez, I. Y.; Van Hal, J. W.; Whitmire, K. H., Metal Cluster Catalysis: A Kinetic and Mechanistic Study of the Carbonylation of Methanol to Give Methyl Formate as Catalyzed by [Et4N]2[Fe3(CO)9E] (E = S, Se, Te). Organometallics 2003, 22, 1914-1922, DOI: 10.1021/om020548+.

  84. 84.Bachman, R. E.; Whitmire, K. H.; Thurston, J. H.; Gulea, A.; Stavila, O.; Stavila, V., Bismuth ladder polymers: structural and thermal studies of [Bi(OCH2CH2)3N]n and [(BixTb1-x(O2C2H2)3N.2H2O]n. Inorg. Chim.Acta 2003, 346, 249-255, DOI: 10.1016/S0020-1693(02)01381-6.

  85. 85.Xu, L.; Whitmire, K. H., Hybrid Metal Carbonyl-Oxide Clusters: Synthesis and Structure of [Et4N]2[(OC)5WSbW3(CO)9(μ3-OMe)2(μ3-O)WO2(OR)] (R = Me, H). Organometallics 2002, 21, 2581-2583, DOI: 10.1021/om020129c.

  86. 86.Whitmire, K. H.; Derringer, D. R.; Kongkasuwan, K. R., Tris[bis(diphenylphosphino)methane-k2P,P']rhenium(I) perrhenate. Acta Cryst. 2002, E58, m363-m365, DOI: 10.1107/S1600536802010838.

  87. 87.Thurston, J. H.; Whitmire, K. H., Heterobimetallic Bismuth-Transition Metal Salicylate Complexes as Molecular Precursors for Ferroelectric Materials. Synthesis and Structure of Bi2M2(sal)4(Hsal)4(OR)4 (M = Nb, Ta; R = CH2CH3, CH(CH3)2), Bi2Ti3(sal)8(Hsal)2, and Bi2Ti4(OiPr)(sal)10(Hsal) (sal = O2CC6H4-2-O; Hsal = O2CC6H4-2-OH). Inorg. Chem. 2002, 41, 4194-4205, DOI: 10.1021/ic0255454.

  88. 88.Thurston, J. H.; Marlier, E. M.; Whitmire, K. H., Towards a molecular model for bismuth(III) subsalicylate. Synthesis and solid-state structure of [Bi(Hsal)3(bipy)(C7H8)]2 and [Bi(Hsal)(sal)(1,10-phenanthroline)(C7H8)]2. J. Chem. Soc., Chem. Comm. 2002, 2834-2835, DOI: 10.1039/b209188g.

  89. 89.Qian, D.-Q.; Shine, H. J.; Guzman-Jimenez, I. Y.; Thurston, J. H.; Whitmire, K. H., Mono- and Bisadducts from the Addition of Thianthrene Cation Radical Salts to Cycloalkenes and Alkenes. J. Org. Chem. 2002, 67, 4030-4039, DOI: 10.1021/jo0104633.

  90. 90.Qian, D.-Q.; Liu, B.; Shine, H. J.; Guzman-Jimenez, I. Y.; Whitmire, K. H., Ring-opening reactions of 5-(aryl)thianthrenium bromides with aryl thiolates. J. Phys. Org. Chem. 2002, 15, 139-147, DOI: 10.1002/poc.462.

  91. 91.Mukhopadhyay, U.; Thurston, J. H.; Whitmire, K. H.; Khokhar, A. R., Synthesis and characterization of cis-bis-heptamethyleneimine platinum(II) dicarboxylate complexes: crystal structure of cis-[Pt(heptamethyleneimine)2(malonate)].H2O. Polyhedron 2002, 21, 2369-2374, DOI: 10.1016/S0277-5387(02)01214-7.

  92. 92.Ali, M. S.; Thurston, J. H.; Whitmire, K. H.; Khokhar, A. R., Synthesis and characterization of platinum(II) and (IV) complexes containing hexamethyleneimine ligand: crystal structure of [PtII(hexamethyleneimine)2(cyclobutanedicarboxylato)].H2O. Polyhedron 2002, 21, 2659-2665, DOI: 10.1016/S0277-5387(02)01263-9.

  93. 93.Ali, M. S.; Mukhopadhyay, U.; Shirvani, S. M.; Thurston, J.; Whitmire, K. H.; Khokhar, A. R., Homopiperazine platinum(II) complexes containing substituted sulfide groups: crystal structure of [PtII(homopiperazine)(diphenylsulfide)Cl]NO3. Polyhedron 2002, 21, 125-131, DOI: 10.1016/S0277-5387(01)00967-6.

  94. 94.Litosh, V. A.; Saini, R. K.; Guzman-Jimenez, I. Y.; Whitmire, K. H.; Billups, W. E., Reactions of Cycloproparenes with Metal Carbenes. Org. Lett. 2001, 3, 65-66, DOI: 10.1021/ol0067787.

  95. 95.Guzman-Jimenez, I. Y.; Whitmire, K. H.; Umezama-Vizzini, K.; Colorado, R.; Do, J.; Jacobson, A.; Lee, T. R.; Hong, S.; Mirkin, C. A., Self-assembly of organometallic clusters onto the surface of gold. Thin Solid Films 2001, 401, 131-137, DOI: 10.1016/S0040-6090(01)01616-9.

  96. 96.Ali, M. S.; Powers, C. A.; Whitmire, K. H.; Guzman-Jimenez, I.; Khokhar, A. R., Synthesis, characterization, and representative crystal structure of lipophilic platinumII (homopiperazine)carboxylate complexes. J. Coord. Chem. 2001, 52, 273-287, DOI: 10.1080/00958970108022593.

  97. 97.Whitmire, K. H.; Hoppe, S.; Sydora, O.; Jolas, J. L.; Jones, C. M., Oligomerization and Oxide Formation in Bismuth Aryl Alkoxides: Synthesis and Characterization of Bi4(μ4-O)(μ-OC6F5)6{μ3-OBi(μ-OC6F5)3}2(C6H5CH3), Bi8(μ4-O)2(μ3-O)2(μ-OC6F5)16, Bi6(μ3-O)4(μ3-OC6F5){μ3-OBi(OC6F5)4}3, NaBi4(μ3-O)2(OC6F5)9(THF)2, and Na2Bi4(μ3-O)2(OC6F5)10(THF)2. Inorg. Chem. 2000, 39, 85-97, DOI: 10.1021/ic990431m.

  98. 98.Whitmire, K. H.; Guzman-Jimenez, I. Y.; Saillard, J.-Y.; Kahlal, S., Synthesis, characterization, structural and theoretical analysis of a series of electron deficient, monomeric thallium iron carbonylate isostructural and isolobal to diiron nonacarbonyl. J. Organomet. Chem. 2000, 614-615, 243-254, DOI: 10.1016/S0022-328X(00)00629-X.

  99. 99.Khan, S. R. A.; Huang, S.; Shamsuddin, S.; Inutsuka, S.; Whitmire, K. H.; Siddik, Z. H.; Khokhar, A. R. A. R., Synthesis, characterization and cytotoxicity of new platinum(IV) axial carboxylate complexes: crystal structure of potential antitumor agent [PtIV(trans-1R,2R-diaminocyclohexane)trans(acetate)2Cl2]. Bioorg. Med. Chem. 2000, 8, 515-521, DOI: 10.1016/S0968-0896(99)00313-2.

  100. 100.Khan, S. R. A.; Guzman-Jimenez, I.; Whitmire, K. H.; Khokhar, A. R., Synthesis and characterization of piperidine platinum(II) complexes with dicarboxylates: crystal and molecular structure of cis-[Pt(piperidine)2Cl2]·H2O. Polyhedron 2000, 19, 975-981, DOI: 10.1016/S0277-5387(00)00348-X.

  101. 101.Khan, S. R. A.; Guzman-Jimenez, I.; Whitmire, K. H.; Khokhar, A. R., Synthesis and characterization of platinum(II) complexes with 3-methylpiperidine: crystal and molecular structure of [Pt(3-methylpiperidine)2(malonato)]∙H2O. Polyhedron 2000, 19, 983-989, DOI: 10.1016/S0277-5387(00)00351-X.

  102. 102.Engel, P. S.; Pan, L.; Whitmire, K. H.; Guzman-Jimenez, I.; Willcott, M. R.; Smith, W. B., Mechanistic Studies of a Linear Trisazoalkane, a New Azimine, and a Bicyclic Triaziridine. Azoalkane Homolysis into Seven Fragments. J. Org. Chem. 2000, 65, 1016-1021, DOI: 10.1021/jo991439g.

  103. 103.Whitmire, K. H.; Hutchison, J. C.; Gardberg, A.; Edwards, C., Triethanolamine complexes of copper. Inorg. Chim. Acta 1999, 294, 153-162, DOI: 10.1016/S0020-1693(99)00274-1.

  104. 104.Stark, J. L.; Harms, B.; Guzman-Jimenez, I.; Whitmire, K. H.; Gautier, R.; Halet, J.-F.; Saillard, J.-Y., Different Ways To Distort a Tetracapped Tetrahedron on Route to Forming an E4M4 Cubane: The Case of [E4(Pd(PPh2Me)2)4][Ph2EX2]2 (E = Sb, X = Cl; E = Bi, X = Br). J. Am. Chem. Soc. 1999, 121, 4409-4418, DOI: 10.1021/ja982902u.

  105. 105.Lee, W. K.; Liu, B.; Park, C. W.; Shine, H. J.; Guzman-Jimenez, I. Y.; Whitmire, K. H., Addition of thianthrene cation radical to cycloalkenes. An unexpected monoadduct. J. Org. Chem. 1999, 64, 9206-9210. (erratum ibid.  2001, 66, 1064), DOI: 10.1021/jo9911241.

  106. 106.Guzman-Jimenez, I. Y.; Whitmire, K. H., trans-Dichlorobis(methyldiphenylphosphine-P)palladium(II). Acta Crystallogr., Sect. C: Cryst. Struct. Commun. 1999, C55, i, IUC9900028, DOI: 10.1107/S0108270199099709.

  107. 107.Ali, M. S.; Whitmire, K. H.; Toyomasu, T.; Siddik, Z. H.; Khokhar, A. R., Preparation, characterization, and antitumor activity of new cisplatin analogs with homopiperazines: crystal structure of [PtII(1-methylhomopiperazine)(methylmalonato)] . 2H2O. J. Inorg. Biochem. 1999, 77, 231-238, DOI: 10.1016/S0162-0134(99)00208-1.

  108. 108.Zouchoune, B.; Ogliaro, F.; Halet, J.-F.; Saillard, J.-Y.; Eveland, J. R.; Whitmire, K. H., Bonding Analysis in Inorganic Transition-Metal Cubic Clusters. 3. Metal-Centered Tetracapped M9(μ5-E)4Ln Species with a Tetragonal Distortion. Inorg. Chem. 1998, 37, 865-875, DOI: 10.1021/IC970715B.

  109. 109.Whitmire, K. H., Organotransition Metal Compounds with Element to Transition Metal Bonds. In The Chemistry of Arsenic, Antimony and Bismuth, Norman, N. C., Ed. Blackie Academic and Professional Books: Glasgow, 1998; pp 345-402.

  110. 110.Whitmire, K. H., Main group-transition metal cluster compounds of the group 15 elements. Adv. Organomet. Chem. 1998, 42, 1-145, DOI.

  111. 111.van Hal, J. W.; Whitmire, K. H., Site-directed alkylation of [EFe3(CO)9]2- (E = S, Se, Te) mediated by the chalcogenide. Synthesis, spectroscopic characterization, and reactivity of [PPN][MeFe3(CO)9E] (E = Se, Te). Organometallics 1998, 17, 5197-5201, DOI: 10.1021/om980428v.

  112. 112.van Hal, J. W.; Stark, J. L.; Whitmire, K. H., Hydride abstraction from [PPN]2[HSb{Fe(CO)4}3] by alkyl iodides. Synthesis and characterization of [PPN][Sb(Me)I{Fe(CO)4}2]. J. Organomet. Chem. 1998, 557, 163-167, DOI: 10.1016/S0022-328X(97)00681-5.

  113. 113.Shamsuddin, S.; Santillan, C. C.; Stark, J. L.; Whitmire, K. H.; Siddik, Z. H.; Khokhar, A. R., Synthesis, characterization, and antitumor activity of new platinum(IV) trans-carboxylate complexes: crystal structure of [Pt(cis-1,4-DACH)trans-(acetate)2Cl2]. J. Inorg. Biochem. 1998, 71, 29-35, DOI: 10.1016/S0162-0134(98)10029-6.

  114. 114.Hoppe, S.; Whitmire, K. H., Synthesis and Structure of Pentavalent Bismuth(V) Alkoxides and Ligand Redistribution Equilibria in Solution. Organometallics 1998, 17, 1347-1354, DOI: 10.1021/OM970760R.

  115. 115.Guzman-Jimenez, I. Y.; Whitmire, K. H., Bis(tetraethylammonium) tetra-μ-carbonyl-icosacarbonylhexairon-dithallate(2 Fe-Fe)(8 Fe-Tl)(2-). Acta Crystallogr., Sect. C: Cryst. Struct. Commun. 1998, C54, i, IUC9800053, DOI: 10.1107/S0108270198099326.

  116. 116.Engel, P. S.; Duan, S.; Whitmire, K. H., Structure and Stability of an Azoalkane-Iodine Complex. J. Org. Chem. 1998, 63, 5666-5667, DOI: 10.1021/JO980265K.

  117. 117.Whitmire, K. H.; Hutchison, J. C.; Burkart, M. D.; Lee, J.; Ezenwa, S.; McKnight, A. L.; Jones, C. M.; Bachman, R. E., Main group-transition metal carbonyl complexes. Inorg. Synth. 1997, 31, 220-228, DOI: 10.1002/9780470132623.ch34.

  118. 118.van, H. J. W.; Whitmire, K. H., Bis[bis(triphenylphosphine)iminium] di-μ-thiobis[(pentasulfido)ferrate(III)]. Acta Crystallogr., Sect. C: Cryst. Struct. Commun. 1997, C53, x, IUC9700008, DOI: 10.1107/S0108270197099484.

  119. 119.van Hal, J. W.; Alemany, L. B.; Whitmire, K. H., Solution Dynamics of Thallium-Metal Carbonyl Compounds Using 205Tl NMR Spectroscopy. Inorg. Chem. 1997, 36, 3152-3159, DOI: 10.1021/IC961203K.

  120. 120.Stark, J. L.; Whitmire, K. H., trans-Dibromobis(triphenylphosphine)palladium(II) tetrahydrofuran solvate and trans-dichlorobis(triphenylphosphine)palladium(II) bis(chloroform) solvate. Acta Crystallogr., Sect. C: Cryst. Struct. Commun. 1997, C53, xi, IUC9700007/1-2, DOI: 10.1107/S0108270197099502.

  121. 121.Shamsuddin, S.; van Hal, J. W.; Stark, J. L.; Whitmire, K. H.; Khokhar, A. R., Synthesis and Characterization of Novel Axial Dichloroplatinum(IV) Cisplatin Analogs: Crystal Structure of an Axial Dichloro Complex [Pt(cis-1,4-DACH)(trans-Cl2)(CBDCA)].1/2MeOH. Inorg. Chem. 1997, 36, 5969-5971, DOI: 10.1021/IC970416M.

  122. 122.Jolas, J. L.; Hoppe, S.; Whitmire, K. H., Oligomerization and Oxide Formation in Bismuth Aryloxides: Synthesis, Characterization, and Structures of [NaBi(OC6F5)4(THF)]∞ and Na4Bi2(μ6-O)(OC6F5)8(THF)4. Inorg. Chem. 1997, 36, 3335-3340, DOI: 10.1021/IC961481J.

  123. 123.Eveland, J. R.; Whitmire, K. H., Synthesis and characterization of the carbide cubane cluster [Fe3(CO)9Te4(μ3-CTeBr4)] with an unusual tetrahedral CTe4 unit. Angew. Chem. Int. Ed. Eng. 1997, 36, 1193-1194, DOI: 10.1002/anie.199711931.

  124. 124.Eveland, J. R.; Saillard, J.-Y.; Whitmire, K. H., Effect of Hybridization on Structure and Bonding of Cluster Compounds Possessing a Square-Pyramidal Fe3(CO)9E2 Core (E = Element of Group 15 or 16). Inorg. Chem. 1997, 36, 330-334, DOI: 10.1021/IC960243L.

  125. 125.Eveland, J. R.; Saillard, J.-Y.; Whitmire, K. H., Halide Ion Addition to Bismuth-Containing Iron Carbonyl Compounds: Synthesis and Characterization of the Two Bridged-Butterfly Cluster Compounds [Et4N][(μ-H)Fe2(CO)6Bi2{μ-Fe(CO)4}] and [{PhCH2NMe3}{(μ-H)Fe2(CO)6Bi2(μ-Cl)2}]n and Stabilization of Reduced-Hypervalent Bismuth Centers by Coordination to a Metal Center in [PhCH2NMe3]3[Bi3Cl4(μ-Cl)4{Fe(CO)3}]. Inorg. Chem. 1997, 36, 4387-4396, DOI: 10.1021/IC9609721.

  126. 126.Das, G.; Shukla, R.; Mandal, S.; Singh, R.; Bharadwaj, P. K.; van Hal, J.; Whitmire, K. H., Syntheses and X-Ray Structures of Mixed-Ligand Salicylaldehyde Complexes of Mn(III), Fe(III), and Cu(II) Ions: Reactivity of the Mn(III) Complex Toward Primary Monoamines and Catalytic Epoxidation of Olefins by the Cu(II) Complex. Inorg. Chem. 1997, 36, 323-329, DOI: 10.1021/IC9510371.

  127. 127.Eveland, J. R.; Whitmire, K. H.; Saillard, J.-Y., Isolation of a Bismuth Chloride-Iron Carbonyl Adduct: Synthesis and Structural Characterization of [PhCH2NMe3]2[Bi2Cl4(μ-Cl)2{μ-Fe(CO)4}]. Inorg. Chem. 1996, 35, 4400-4405, DOI: 10.1021/IC951262I.

  128. 128.Eveland, J. R.; Whitmire, K. H., Synthesis and characterization of the novel iron carbonyl tellurium chloride cluster [Fe2(CO)6(μ-Cl)(μ-TeCl)2]2[η2,μ2,μ2-Te2Cl10], and its decomposition to the Zintl ion complex [Fe2(CO)6(η2,μ2,μ2-Te4)(μ-TeCl2)]. Angew. Chem. Int. Ed. Eng. 1996, 35, 741-3, DOI: 10.1002/anie.199607411.

  129. 129.Eveland, J. R.; Whitmire, K. H., Complexes of bismuth(III) chloride with oxygen donor ligands. Structural characterization of BiCl3.3THF, BiCl3.diglyme and BiCl3.diethylcarbitol. Inorg. Chim. Acta 1996, 249, 41-46, DOI: 10.1016/0020-1693(96)05024-4.

  130. 130.Whitmire, K. H., Perspectives on bismuth alkoxide chemistry and its relation to bismuth-oxide-based materials and catalysts. Chemtracts: Inorg. Chem. 1995, 7, 167-181, DOI.

  131. 131.Whitmire Kenton, H., Iron Carbonyls without Hydrocarbon Ligands. In Comprehensive Organometallic Chemistry II, Abel, E.W.; Stone, F. G. A.; Wilkinson, G., Eds. Elsevier Science, Ltd.: Oxford, UK, 1995; Vol. 7, pp 1-100.

  132. 132.van Hal, J. W.; Whitmire, K. H.; Zouchoune, B.; Halet, J.-F.; Saillard, J.-Y., Synthesis, Characterization, and Molecular Orbital Analysis of [Et4N]2[(OC)5MoAsMo3(CO)9(μ3-OR)3Mo(CO)3] (R = Me, Et). X-ray Structure of [Et4N]2[(OC)5MoAsMo3(CO)9(μ3-OMe)3Mo(CO)3].0.6thf. Inorg. Chem. 1995, 34, 5455-60, DOI: 10.1021/ic00126a014.

  133. 133.Bachman, R. E.; Whitmire, K. H.; van Hal, J., Effect of Charge on Structure: Stepwise Protonation of [EFe3(CO)9]2- (E = Se, Te) and Isolation of a Novel Mixed-Metal Cluster [TeFe3(CO)9(μ3-CuCl)]2-. Organometallics 1995, 14, 1792-801, DOI: 10.1021/om00004a036.

  134. 134.Bachman, R. E.; Whitmire, K. H., Synthesis and Structure of Carbonyl-Metalated Organobismuth Complexes. Inorg. Chem. 1995, 34, 1542-51, DOI: 10.1021/ic00110a037.

  135. 135.Bachman, R. E.; Miller, S. K.; Whitmire, K. H., Structural and Reactivity Consequences of the Presence of Lone Pairs in Main-Group-Transition-Metal Cluster Compounds: Conversion of [HAs{Fe(CO)4}3]2- into [Fe3(CO)9{μ3-AsFe(CO)4}2]2. Organometallics 1995, 14, 796-803, DOI: 10.1021/om00002a029.

  136. 136.Bachman, R. E.; Maughon, B. R.; McCord, D. J.; Whitmire, K. H.; Billups, W. E., (Bromodichloromethyl)phenylmercury. Acta Cryst. 1995, C51, 2033-5, DOI: 10.1107/S0108270195004501.

  137. 137.Whitmire, K. H.; Eveland, J. R., Structural characterization of two large bismuth-cobalt carbonyl clusters: (PPN)2[Bi4Co9(CO)8(μ-CO)8].2THF and (PPN)2[Bi8Co14(CO)12(μ-CO)8].1.08THF. J. Chem. Soc., Chem. Comm. 1994, 1335-6, DOI: 10.1039/C39940001335.

  138. 138.Whitmire, K. H., Bismuth:  Organometallic Chemistry. In Encyclopedia of Inorganic Chemistry, King, R. B., Ed. John Wiley: New York, 1994; Vol. vol. 1, pp 292-300.

  139. 139.Whitmire, K. H., Bismuth:  Inorganic Chemistry. In Encyclopedia of Inorganic Chemistry, King, R. B., Ed. John Wiley: New York, 1994; Vol. vol. 1, pp 280-291.

  140. 140.Shukla, R.; Bharadwaj, P. K.; Van Hal, J.; Whitmire, K. H., Mononuclear manganese(III) complexes with imine/amine and phenolate ligation: x-ray structural, spectroscopic and electrochemical studies. Polyhedron 1994, 13, 2387-94, DOI: 10.1016/S0277-5387(00)88151-6.

  141. 141.Kahlal, S.; Halet, J.-F.; Saillard, J.-Y.; Whitmire, K. H., Bonding analysis of electron-rich bridged mixed main-group/transition metal tetrahedral M2E2 organometallic clusters. J. Organomet. Chem. 1994, 478, 1-8, DOI: 10.1016/0022-328X(94)88149-9.

  142. 142.Engel, P. S.; Wu, A.; Whitmire, K. H., 1,2-Azoxy Rearrangement and Fragmentation of b-Azoxy Radicals. J. Am. Chem. Soc. 1994, 116, 4079-80, DOI: 10.1021/ja00088a054.

  143. 143.Ciufolini, M. A.; Rivera-Fortin, M. A.; Zuzukin, V.; Whitmire, K. H., Origin of Regioselectivity in Paterno-Buechi Reactions of Benzoquinones with Alkylidenecycloalkanes. J. Am. Chem. Soc. 1994, 116, 1272-7, DOI: 10.1021/ja00083a013.

  144. 144.Bachman, R. E.; Whitmire, K. H., The Synthesis and Characterization of a Series of Iron Carbonyl Clusters Containing Selenium and Tellurium. Inorg. Chem. 1994, 33, 2527-33, DOI: 10.1021/ic00090a010.

  145. 145.Bachman, R. E.; Whitmire, K. H., Molecular and crystal structure of [Et4N][Cl].2[Fe2(CO)6Te2]. J. Organomet. Chem. 1994, 479, 31-5, DOI: 10.1016/0022-328X(94)84088-1.

  146. 146.Bachman, R. E.; Miller, S. K.; Whitmire, K. H., Synthesis and Structure of an Anionic Arsenic Hydride Complex: [PPN]2[HAs{Fe(CO)4}3].0.5THF. Inorg. Chem. 1994, 33, 2075-6, DOI: 10.1021/ic00088a004.

  147. 147.Jones, C. M.; Burkart, M. D.; Bachman, R. E.; Serra, D. L.; Hwu, S. J.; Whitmire, K. H., Hypervalent bismuth alkoxide dimer complexes: syntheses, structures, and thermal decompositions of [Bi(OCH(CF3)2)2(μ-OCH(CF3)2)(THF)]2 and [Bi(OC6F5)2(μ-OC6F5)Xn]2.zY (X = Y = C7H8, n = 1, z = 1 or 2; X = THF, Y = C6H14, n = 2, z = 0 or 1). Inorg. Chem. 1993, 32, 5136-44, DOI: 10.1021/ic00075a033.

  148. 148.Cassidy, J. M.; Whitmire, K. H.; Kook, A. M., Solution dynamics of tin and lead iron carbonyl compounds and the solid state structure of [Et4N]2[Sn{Fe2(CO)8}{Fe(CO)4}2]. J. Organomet. Chem. 1993, 456, 61-70, DOI: 10.1016/0022-328X(93)83318-P.

  149. 149.Bartik, T.; Bartik, B.; Hanson, B. E.; Whitmire, K. H.; Guo, I., Reactions of trisulfonated triphenylphosphine, TPPTS, with cobalt carbonyls in water. Inorg. Chem. 1993, 32, 5833-7, DOI: 10.1021/ic00077a030.

  150. 150.Bachman, R. E.; Whitmire, K. H., Bis[bis(triphenylphosphine)iminium] decarbonyldimolybdate (Mo-Mo). Acta Crystallogr., Sect. C: Cryst. Struct. Commun. 1993, C49, 327-8, DOI: 10.1107/S0108270192006498.

  151. 151.Bachman, R. E.; Whitmire, K. H., Reduction of tellurium by Na2[Fe(CO)4]: synthesis and reactivity of [PPN]2[Fe2(CO)6(Te2)2]. Organometallics 1993, 12, 1988-92, DOI: 10.1021/om00029a068.

  152. 152.Bachman, R. E.; Whitmire, K. H., Bis[bis(triphenylphosphine)iminium] dodecacarbonylhexanickelate. Acta Cryst. 1993, C49, 1121-3, DOI: 10.1107/S0108270193001830.

  153. 153.Whitmire, K. H.; Jones, C. M.; Burkart, M. D.; Hutchison, J. C.; McKnight, A., Aggregation and hydrolysis reactions of bismuth alkoxides. Mat. Res. Soc. Sym. Proc. 1992, 271, 149-54, DOI: 10.1557/proc-271-149.

  154. 154.Whitmire, K. H.; Hutchison, J. C.; McKnight, A. L.; Jones, C. M., Synthesis and structure of [Et2Bi(OAr)]n (Ar = C6F5, Ph): a new inorganic chain polymer. J. Chem. Soc., Chem. Comm. 1992, 1021-2, DOI: 10.1039/C39920001021.

  155. 155.Whitmire, K. H.; Cassidy, J. M., Two New Crystal Morphologies for Tetraphenyldibismuthine, Bi2Ph4. Acta Cryst. 1992, C48, 917-919, DOI: 10.1107/S0108270191012039.

  156. 156.Meng, X.; Fehlner, T. P.; Whitmire, K. H., Preparation of dinuclear and trinuclear ferraboranes, Fe2(CO)6B2H6 and Fe3H(CO)10BH2. Inorg. Synth. 1992, 29, 269-73, DOI: 10.1002/9780470132609.ch60.

  157. 157.Long, G. J.; Grandjean, F.; Whitmire, K. H., Moessbauer spectroscopic observation of ligand dynamics in [HFe(CO)4]- ions. Proof of a tunneling hydride ligand. Angew. Chem. 1992, 104, 891-3 (See also Angew. Chem., Int. Ed. Engl., 1992, 31(7), 884-6), DOI: 10.1002/ange.19921040724.

  158. 158.Jones, C. M.; Burkart, M. D.; Whitmire, K. H., Dimeric alkoxido bismuth complexes with planar [Bi2(μ-OR)2] units. Synthesis and structure of [{Bi[OCH(CF3)2]3(THF)}2] and [Bi(OC6F5)3(C7H8)]2.2C7H8. Angew. Chem., Int. Ed. Engl. 1992, 31(4), 451-2, DOI: 10.1002/ange.19921040422.

  159. 159.Jones, C. M.; Burkart, M. D.; Whitmire, K. H., Novel aryloxybismuth oxide clusters: x-ray crystal structures of Bi6(μ3-O)7(μ3-OC6F5){Bi(OC6F5)4}3(THF)2 and Bi6(μ3-O)7(μ3-OC6F5){Bi(OC6F5)4}3.2C7H8 (THF = tetrahydrofuran). J. Chem. Soc., Chem. Comm. 1992, 1638-9, DOI: 10.1039/C39920001638.

  160. 160.Cassidy, J. M.; Whitmire, K. H.; Long, G. J., Structure and Moessbauer effect study of [Et4N]2[Fe2(CO)8]. J. Organomet. Chem. 1992, 427, 355-62, DOI: 10.1016/0022-328X(92)80073-7.

  161. 161.Burgess, K.; Ohlmeyer, M. J.; Whitmire, K. H., Stereochemically matched (and mismatched) bisphosphine ligands: DIOP-DIPAMP hybrids. Organometallics 1992, 11, 3588-600, DOI: 10.1021/om00059a023.

  162. 162.Bachman, R. E.; Whitmire, K. H.; Mandal, S.; Bharadwaj, P. K., Dichlorotetrakis(pyridine)nickel(II). Acta Cryst. 1992, C48, 1836-7, DOI: 10.1107/S0108270192001872.

  163. 163.Whitmire, K. H.; Roesky, H. W.; Brooker, S.; Sheldrick, G. M., Carbon-fluorine bond activation in the reaction of bismuth trichloride with sodium 2,4,6-tris(trifluoromethyl)phenoxide. J. Organomet. Chem. 1991, 402, C4-C7, DOI: 10.1016/0022-328X(91)80091-W.

  164. 164.Whitmire, K. H.; Labahn, D.; Roesky, H. W.; Noltemeyer, M.; Sheldrick, G. M., Sterically crowded aryl bismuth compounds: synthesis and characterization of bis[2,4,6-tris(trifluoromethyl)phenyl] bismuth chloride and tris[2,4,6-tris(trifluoromethyl)phenyl] bismuth. J. Organomet. Chem. 1991, 402, 55-66, DOI: 10.1016/0022-328X(91)80081-T.

  165. 165.Whitmire, K. H., A Comparison of Bismuth- and Antimony-containing Transition Metal Cluster Complexes. J. Cluster Sci. 1991, 2, 231-258, DOI: 10.1007/BF00702955.

  166. 166.Cassidy, J. M.; Whitmire, K. H., Syntheses and structures of the phenylbismuth/transition-metal carbonyl compounds [PPN][Ph2BiFe(CO)4], (Ph2Bi)2Fe(CO)4, [PhBiFe(CO)4]2 and Ph2BiMn(CO)5. Inorg. Chem. 1991, 30, 2788-95, DOI: 10.1021/ic00013a016.

  167. 167.Cassidy, J. M.; Whitmire, K. H., Structures of chlorotris(triphenylphosphine)cobalt and chlorotris(triphenylphosphine)nickel toluene solvate (1:1). Acta Cryst. 1991, C47, 2094-8, DOI: 10.1107/S0108270191005498.

  168. 168.Brooker, S.; Edelmann, F. T.; Kottke, T.; Roesky, H. W.; Sheldrick, G. M.; Stalke, D.; Whitmire, K. H., Comparison of the x-ray crystal structure of the sodium and potassium 2,4,6-tris(trifluoromethyl)phenoxides (RO-) and 2,4,6-tris(trifluoromethyl)benzenethiolates (RS-); [Na(OR)(thf)2]2, [K(OR)(thf)2(u-thf)]2, [Na(SR)(thf)2.0.25thf]x and [K(SR)(thf)]x (thf = tetrahydrofuran). J. Chem. Soc., Chem. Comm. 1991, 144-6, DOI: 10.1039/C39910000144.

  169. 169.Billups, W. E.; Lee, G. A.; Arney, B. E., Jr.; Whitmire, K. H., 1,3-Bridged cyclopropenes. J. Am. Chem. Soc. 1991, 113, 7980-4, DOI: 10.1021/ja00021a025.

  170. 170.Albright, T. A.; Yee, K. A.; Saillard, J. Y.; Kahlal, S.; Halet, J. F.; Leigh, J. S.; Whitmire, K. H., Capping considerations in main-group/transition-metal clusters: synthetic, structural, and theoretical discussions of [E2Co4(CO)10(m-CO)-/2- (E = Sb, Bi). Inorg. Chem. 1991, 30, 1179-90, DOI: 10.1021/ic00006a006.

  171. 171.Stalke, D.; Whitmire, K. H., Spectroscopic and structural characterization of 2,4,6-tris(trifluoromethyl)phenyllithium.Et2O: a dimer stabilized by lithium...fluorine contacts. J. Chem. Soc., Chem. Comm. 1990, 833-4, DOI: 10.1039/C39900000833.

  172. 172.Margrave, J. L.; Whitmire, K. H.; Hauge, R. H.; Norem, N. T., Synthesis and characterization of bis(trifluoromethyl)gold m-halide dimers: x-ray structural characterization of [Au(CF3)2(μ-I)]2. Inorg. Chem. 1990, 29, 3252-3, DOI: 10.1021/ic00342a043.

  173. 173.Leigh, J. S.; Whitmire, K. H., The structures of tetrakis(tetracarbonylcobaltio)tin and tetrakis(tetracarbonylcobaltio)lead. Acta Cryst. 1990, C46, 732-6, DOI: 10.1107/S0108270189006025.

  174. 174.Hanson, B. E.; Whitmire, K. H., Exchange of axial and equatorial carbonyl groups in pentacoordinate metal carbonyls in the solid state. The variable temperature magic angle spinning carbon-13 NMR spectroscopy of iron pentacarbonyl, [Ph3PNPPh3][HFe(CO)4], and [NEt4][HFe(CO)4]. J. Am. Chem. Soc. 1990, 112, 974-7, DOI: 10.1021/ja00159a011.

  175. 175.Cassidy, J. M.; Whitmire, K. H., Structures of [(C2H5)4N]2[In2Fe6(CO)24] and [(C2H5)4N][(2,2'-bipyridine)InFe2(CO)8]. Acta Cryst. 1990, C46, 1781-5, DOI: 10.1107/S0108270190000026.

  176. 176.Burgess, K.; Ohlmeyer, M. J.; Whitmire, K. H., Stereochemical assignments via cyclic derivatives: a cautionary note. J. Org. Chem. 1990, 55, 1359-61, DOI: 10.1021/jo00291a051.

  177. 177.Whitmire, K. H.; Shieh, M.; Cassidy, J., Synthesis, characterization, and reactivity of iron carbonyl clusters containing bismuth or antimony. Crystal structures of isomorphous [Et4N][BiFe3Cr(CO)17] and [Et4N][SbFe3Cr(CO)17] and the ring complex Bi2Fe2(CO)8Me2. Inorg. Chem. 1989, 28, 3164-70, DOI: 10.1021/ic00315a018.

  178. 178.Whitmire, K. H., Clusters of Metals and Nonmetals. In Rings, Clusters and Polymers of Main Group and Transition Elements, Roesky, H. W., Ed. Elsevier: Amsterdam, 1989; pp 503-541.

  179. 179.Scholz, J. N.; Engel, P. S.; Glidewell, C.; Whitmire, K. H., Reaction of hydroxylamine with benzenesulfonyl chloride. X-ray crystal structure of Piloty's acid and other benzenesulfonylhydroxylamines. Tetrahedron 1989, 45, 7695-708, DOI: 10.1016/S0040-4020(01)85786-0.

  180. 180.Luo, S.; Whitmire, K. H., Synthesis and characterization of a series of antimony-containing iron carbonyl complexes: [Et4N]3[SbFe4(CO)16], [Et4N]2[HSbFe4(CO)13], [Et4N][H2SbFe4(CO)13], and [Et4N]2[ClSbFe3(CO)12]. Inorg. Chem. 1989, 28, 1424-31, DOI: 10.1021/ic00307a002.

  181. 181.Luo, S.; Whitmire, K. H., Synthesis and structures of two new mixed antimony-iron carbonyl clusters: [R4N][SbFe4(CO)16] (R = Me, Et) and [Et4N]2[Sb2Fe6(CO)20]. J. Organomet. Chem. 1989, 376, 297-310, DOI: 10.1016/0022-328X(89)85140-X.

  182. 182.Leigh, J. S.; Whitmire, K. H.; Yee, K. A.; Albright, T. A., Reversible redox processes in main-group/transition-metal clusters: the [Sb2Co4(CO)10(μ-CO)]-/2- couple. J. Am. Chem. Soc. 1989, 111, 2726-7, DOI: 10.1021/ja00189a063.

  183. 183.Leigh, J. S.; Whitmire, K. H., The structure of hydridotricarbonyl(tricyclohexylphosphine)cobalt(I). Acta Cryst. 1989, C45, 210-12, DOI: 10.1107/S0108270188010960.

  184. 184.Ciufolini, M. A.; Hermann, C. W.; Whitmire, K. H.; Byrne, N. E., Chemoenzymatic preparation of trans-2,6-dialkylpiperidines and of other azacycle building blocks. Total synthesis of (+)-desoxoprosopinine. J. Am. Chem. Soc. 1989, 111, 3473-5, DOI: 10.1021/ja00191a078.

  185. 185.Cassidy, J. M.; Whitmire, K. H., Synthesis and structure of [PPN]2[Tl2Fe6(CO)24]: completion of a series of thallium-iron carbonyl clusters. Inorg. Chem. 1989, 28, 1432-4, DOI: 10.1021/ic00307a003.

  186. 186.Cassidy, J. M.; Whitmire, K. H., Synthesis and structure of Lewis base adducts of thallium iron carbonyl, [Et4N]2[Tl2Fe4(CO)16]. Inorg. Chem. 1989, 28, 1435-9, DOI: 10.1021/ic00307a004.

  187. 187.Cassidy, J. M.; Whitmire, K. H., "Electron-deficient" trigonal-planar tin- and lead-containing iron carbonyl complexes: [Et4N]2[E{Fe(CO)4}3] (E = Sn, Pb). Inorg. Chem. 1989, 28, 2494-6, DOI: 10.1021/ic00311a052.

  188. 188.Whitmire, K. H.; Leigh, J. S.; Luo, S.; Shieh, M.; Fabiano, M. D.; Rheingold, A. L., The isolation and characterization of organoiron clusters containing four-coordinate antimony atoms: [Et4N][Fe3(CO)9(μ-CO){μ3-SbFe(CO)4}] and [Et4N]2[Fe3(CO)9{μ3-SbFe(CO)4}2]. New J. Chem. 1988, 12, 397-404, DOI.

  189. 189.Whitmire, K. H.; Cassidy, J. M.; Rheingold, A. L.; Ryan, R. R., A series of thallium-iron carbonyl cluster molecules: structural comparisons of [Et4N]2[Tl2Fe4(CO)16], [Et4N]4[Tl4Fe8(CO)30], and [Et4N]6[Tl6Fe10(CO)36]. Inorg. Chem. 1988, 27, 1347-53, DOI: 10.1021/ic00281a007.

  190. 190.Whitmire, K. H., The interface of main group and transition metal cluster chemistry. J. Coord. Chem. 1988, 17, 95-204, DOI: 10.1080/00958978808075858.

  191. 191.Leigh, J. S.; Whitmire, K. H., [Cp2Co][Bi[Co(CO)4]4]: a paramagnetic, tetrahedral ten-electron complex of bismuth. Angew. Chem. 1988, 100, 399-400, DOI: 10.1002/ange.19881000309.

  192. 192.Engel, P. S.; Hoque, A. K. M. M.; Scholz, J. N.; Shine, H. J.; Whitmire, K. H., The reaction of 2,3-diazabicyclo[2.2.2]oct-2-ene with stable cation radical salts. J. Am. Chem. Soc. 1988, 110, 7880-2, DOI: 10.1021/ja00231a051.

  193. 193.Whitmire, K. H.; Shieh, M.; Lagrone, C. B.; Robinson, B. H.; Churchill, M. R.; Fettinger, J. C.; See, R. F., Transformations in the bismuth-iron carbonyl cluster system: importance of oxidation/reduction reactions. Crystal structures of tris(tetramethylammonium)tridecacarbonyldibismuthtetraferrate(2-) chloride and tetraethylammonium decacarbonyldibismuthcobaltdiferrate(1-). Inorg. Chem. 1987, 26, 2798-807, DOI: 10.1021/ic00264a016.

  194. 194.Whitmire, K. H.; Leigh, J. S.; Gross, M. E., Isolation and characterization of the strained cluster complex, (μ3-Bi)Co3(CO)6(μ-CO)3; the application of thermogravimetric analysis to rational cluster reactions. J. Chem. Soc., Chem. Comm. 1987, 926-7, DOI: 10.1039/C39870000926

  195. 195.Whitmire, K. H.; Lagrone, C. B.; Churchill, M. R.; Fettinger, J. C.; Robinson, B. H., Oxidation/reduction chemistry of iron carbonyl clusters containing germanium, tin, or lead: crystal and molecular structures of [Et4N]2[Fe3(CO)9(μ3-CO)(μ3-Ge{Fe(CO)4})] and Pb[Fe2(CO)8]2. Inorg. Chem. 1987, 26, 3491-9, DOI: 10.1021/ic00268a017.

  196. 196.Stanghellini, P. L.; Sailor, M. J.; Kuznesof, P.; Whitmire, K. H.; Hriljac, J. A.; Kolis, J. W.; Zheng, Y.; Shriver, D. F., Vibrational frequencies associated with the carbide ligand in iron butterfly clusters. Inorg. Chem. 1987, 26, 2950-4, DOI: 10.1021/ic00265a007.

  197. 197.Rheingold, A. L.; Geib, S. J.; Shieh, M.; Whitmire, K. H., Synthesis and characterization of a double-spiro μ4-antimony metal carbonyl complex, [Fe2(CO)8(μ4-Sb)]2[Fe2(CO)6]. Inorg. Chem. 1987, 26, 463-5, DOI: 10.1021/ic00250a024.

  198. 198.Whitmire, K. H.; Ryan, R. R.; Wasserman, H. J.; Albright, T. A.; Kang, S. K., An electron-deficient thallium Zintl-metal carbonylate: structure and bonding of [Et4N]6[Tl6Fe10(CO)36]. J. Am. Chem. Soc. 1986, 108, 6831-2, DOI: 10.1021/ja00281a076.

  199. 199.Whitmire, K. H.; Raghuveer, K. S.; Churchill, M. R.; Fettinger, J. C.; See, R. F., Effect of charge on bond formation and cleavage in main-group-transition-metal clusters: the reactions of Bi2Fe3(CO)9 with [Fe(CO)4]2- and [Co(CO)4]-. J. Am. Chem. Soc. 1986, 108, 2778-80, DOI: 10.1021/ja00270a060.

  200. 200.Whitmire, K. H.; Lee, T. R.; Lewis, E. S., Kinetics and mechanism of the reaction of [Et4N][HFe(CO)4] and alkyl halides. The unexpected formation of acetone. Organometallics 1986, 5, 987-94, DOI: 10.1021/om00136a025.

  201. 201.Whitmire, K. H.; Lagrone, C. B.; Rheingold, A. L., Lewis basicity of carbonyl oxygen in the presence of a heteroatom: reaction of decacarbonylbismuthtriferrate(1-) with trifluoromethyl methylsulfonate. Inorg. Chem. 1986, 25, 2472-4, DOI: 10.1021/ic00234a039.

  202. 202.Whitmire, K. H.; Albright, T. A.; Kang, S. K.; Churchill, M. R.; Fettinger, J. C., Structural and theoretical discussion of tridecacarbonyltetrabismuthtetraferrate(2-): application of MO and Teo electron counting theories to a Zintl-metal carbonylate. Inorg. Chem. 1986, 25, 2799-805, DOI: 10.1021/ic00236a029.

  203. 203.Lagrone, C. B.; Whitmire, K. H.; Churchill, M. R.; Fettinger, J. C., Synthesis and characterization of an iron carbonyl cluster containing lead: crystal and molecular structure of [Et4N]2[Pb{Fe(CO)4}2{Fe2(CO)8}]. Inorg. Chem. 1986, 25, 2080-5, DOI: 10.1021/ic00232a034.

  204. 204.Churchill, M. R.; Fettinger, J. C.; Whitmire, K. H.; Lagrone, C. B., X-ray structural characterization of [Et4N+]3[BiFe4(CO)163-]. J. Organomet. Chem. 1986, 303, 99-109, DOI: 10.1016/0022-328X(86)80115-21095.

  205. 205.Chang, S. C.; Kafafi, Z. H.; Hauge, R. H.; Whitmire, K. H.; Billups, W. E.; Margrave, J. L., Infrared spectrum of hexacarbonylbis(μ-carbonyl)(μ-methylene)diiron, Fe2(CO)6(μ-CO)2(μ-CH2), in cryogenic matrixes. Inorg. Chem. 1986, 25, 4530-3, DOI: 10.1021/ic00245a016.

  206. 206.Whitmire, K. H.; Lee, T. R., Carbon-13 NMR studies of some iron carbonyls: an unexpected trend in the chemical shifts of disubstituted complexes. J. Organomet. Chem. 1985, 282, 95-106, DOI: 10.1016/0022-328X(85)87145-X1985.

  207. 207.Whitmire, K. H.; Churchill, M. R.; Fettinger, J. C., Synthesis and crystal structure of the bismuth-iron carbonyl cluster [Et4N]2[Bi4Fe4(CO)13]. Discovery of a hybrid Zintl-metal carbonyl cluster. J. Am. Chem. Soc. 1985, 107, 1056-7, DOI: 10.1021/ja00290a050.

  208. 208.Churchill, M. R.; Fettinger, J. C.; Whitmire, K. H., Synthesis and x-ray crystallographic characterization of (μ3-Bi)2Fe3(CO)9: a reformulation of Hieber's Bi2Fe5(CO)20. J. Organomet. Chem. 1985, 284, 13-23, DOI: 10.1016/0022-328X(85)80008-5.

  209. 209.Whitmire, K. H.; Lagrone, C. B.; Churchill, M. R.; Fettinger, J. C.; Biondi, L. V., Synthesis and characterization of an iron carbonyl cluster containing bismuth: crystal and molecular structure of tetraethylammonium (μ3-bismuthido)nonacarbonyl(μ3-carbonyl)-triangulo-triferrate(1-), [Et4N][(μ3-Bi)Fe3(CO)9(μ3-CO)], a closo cluster of the first transition series with a large heteroatom. Inorg. Chem. 1984, 23, 4227-32, DOI: 10.1021/ic00193a026.

  210. 210.Johnson, B. F. G.; Lewis, J.; Raithby, P. R.; Azman, S. N.; Syed-Mustaffa, B.; Taylor, M. J.; Whitmire, K. H.; Clegg, W., Synthesis of mixed-metal clusters by the reaction of the unsaturated cluster decacarbonylbis(m-hydrido)triosmium with transition metal hydrides: the x-ray crystal structures of [Os3H3(CO)10[Cu(PPh3)]] and [Os3H3(CO)11[Ir(PPh3)]]. J. Chem. Soc., Dalton Trans. 1984, 2111-18, DOI: 10.1039/DT9840002111.

  211. 211.Bogdan, P. L.; Whitmire, K. H.; Kolis, J. W.; Shriver, D. F.; Holt, E. M., Protonation and protolysis of [Fe4(CO)12(CCH3)]. J. Organomet. Chem. 1984, 272, 169-77, DOI: 10.1016/0022-328X(84)80464-7.

  212. 212.Johnson, B. F. G.; Lewis, J.; Nicholls, J. N.; Puga, J.; Whitmire, K. H., Formation of new halo mixed-metal clusters by oxidative addition of triphenylphosphinegold(I) halides to carbidopentadecacarbonylpentaruthenium: crystal and molecular structures of [Ru5C(CO)15{μ-Au(PPh3)}Cl] and [Ru5C(CO)14{μ-Au(PPh3)}(μ-Br)]. J. Chem. Soc., Dalton Trans. 1983, 787-97, DOI: 10.1039/DT9830000787.

  213. 213.Johnson, B. F. G.; Lewis, J.; Nelson, W. J. H.; Puga, J.; Raithby, P. R.; Whitmire, K. H., Synthesis, reactivity, and x-ray crystal structure of the cationic cluster complex bis(acetonitrile)trihydridotetrakis[tricarbonylosmium(I)] tetrafluoroborate. J. Chem. Soc., Dalton Trans. 1983, 1339-44, DOI: 10.1039/DT9830001339.

  214. 214.Goudsmit, R. J.; Johnson, B. F. G.; Lewis, J.; Raithby, P. R.; Whitmire, K. H., Synthesis, reactivity, and molecular structure of the raft complex [Os6(μ3-O)(μ3-CO)(CO)18]. J. Chem. Soc., Chem. Comm. 1983, 246-7, DOI: 10.1039/C39830000246.

  215. 215.Whitmire, K. H. The proton-induced reduction of carbon monoxide in polynuclear iron carbonyl complexes. PhD dissertation, Northwestern University, Evanston, Illinois, 1982.

  216. 216.Whitmire, K.; Ross, J.; Cooper, C. B., III; Shriver, D. F., Bis[μ-nitrido-bis(triphenylphosphorus)(+)] tridecacarbonyltetraferrate(2-) or [bis(triphenylphosphine)iminium tridecacarbonyltetraferrate](2-) [PPN]2[Fe4(CO)13]. Inorg. Synth. 1982, 21, 66-9, DOI: 10.1002/9780470132524.ch14.

  217. 217.Shriver, D. F.; Whitmire, K. H., Iron Compounds without Hydrocarbon Ligands. In Comprehensive Organometallic Chemistry, Wilkinson, G., Ed. Pergamon Press: Oxford, UK, 1982; Vol. 4, pp 243-329.

  218. 218.Kolis, J. W.; Holt, E. M.; Drezdzon, M.; Whitmire, K. H.; Shriver, D. F., A reactive three-metal carbide cluster precursor, [Fe3(CO)9(CCO)]2-. J. Am. Chem. Soc. 1982, 104, 6134-5, DOI: 10.1021/ja00386a058.

  219. 219.Johnson, B. F. G.; Lewis, J.; Nelson, W. J. H.; Puga, J.; Raithby, P. R.; Schroder, M.; Whitmire, K. H., Synthesis and x-ray crystal structure of the cluster cation [Os4(μ2-H)3(CO)12(NCMe)2]+: an example of an unsupported butterfly tetraosmium geometry. J. Chem. Soc., Chem. Comm. 1982, 610-12, DOI: 10.1039/C39820000610.

  220. 220.Holt, E. M.; Whitmire, K. H.; Shriver, D. F., Nucleophilic attack and structural rearrangements in some iron carbonyl cluster carbides. Syntheses, structures, and reactions of the tetrahedral four-iron clusters [Fe4(CO)12(m3-COMe)]- and [Fe4(CO)12(CMe)]. J. Am. Chem. Soc. 1982, 104, 5621-6, DOI: 10.1021/ja00385a010.

  221. 221.Goudsmit, R. J.; Johnson, B. F. G.; Lewis, J.; Raithby, P. R.; Whitmire, K. H., Synthesis and x-ray crystal structure of the cluster [Os6(CO)17[P(OMe)3]4], an example of a hexa-metal planar complex. J. Chem. Soc., Chem. Comm. 1982, 640-2, DOI: 10.1039/c39820000640.

  222. 222.Drezdzon, M. A.; Whitmire, K. H.; Bhattacharyya, A. A.; Hsu, W. L.; Nagel, C. C.; Shore, S. G.; Shriver, D. F., Proton-induced reduction of CO to CH4 in homonuclear and heteronuclear metal carbonyls: a survey of the influence of the metal and nuclearity. J. Am. Chem. Soc. 1982, 104, 5630-3, DOI: 10.1021/ja00385a012.

  223. 223.Braga, D.; Johnson, B. F. G.; Lewis, J.; Mace, J. M.; McPartlin, M.; Puga, J.; Nelson, W. J. H.; Raithby, P. R.; Whitmire, K. H., The reaction of nitrosyl cation with some anions of osmium and ruthenium: synthesis and x-ray characterization of [H3Os4(CO)12(μ2-NO)] and [HRu4N(CO)11P(OMe)3]. J. Chem. Soc., Chem. Comm. 1982, 1081-3, DOI: 10.1039/C39820001081.

  224. 224.Whitmire, K. H.; Shriver, D. F., (μ-H)Fe4(CO)12(η2-COH): evidence for a protonated η2-CO complex as an intermediate in the proton-induced reduction of carbon monoxide. J. Am. Chem. Soc. 1981, 103, 6754-5, DOI: 10.1021/ja00412a0421.

  225. 225.Holt, E. M.; Whitmire, K. H.; Shriver, D. F., The role of metal cluster interactions in the proton-induced reduction of carbonyl. The crystal structures of [PPN][HFe4(CO)12C] and HFe4(CO)12(η2-COCH3). J. Organomet. Chem. 1981, 213, 125-37, DOI: 10.1016/S0022-328X(00)93954-8.

  226. 226.Whitmire, K.; Shriver, D. F.; Holt, E. M., Structural and isotope tracer study of the proton induced reduction of carbonyl in [Fe4(CO)11(μ-CO)(μ3-COMe)]-; x-ray crystal structure of [Fe4H(CO)12COMe]. J. Chem. Soc., Chem. Comm. 1980, 780-1, DOI: 10.1039/C39800000780.

  227. 227.Whitmire, K.; Shriver, D. F., A new reaction for the conversion of carbon monoxide into methane: proton-induced reduction of carbon monoxide in a metal carbonyl cluster, [Fe4(CO)132-]. J. Am. Chem. Soc. 1980, 102, 1456-7, DOI: 10.1021/ja00412a042Whitmire.

  228. 228.Holt, E. M.; Whitmire, K.; Shriver, D. F., O-Alkylation and structural rearrangement of carbonyl ligands in [Fe4(CO)9(μ-CO)3(μ3-CO)]2-; x-ray crystal structure of [N(PPh3)2][Fe4(CO)11(μ-CO)(μ3-COMe)]. J. Chem. Soc., Chem. Comm. 1980, 778-9, DOI: 10.1039/C39800000778.

  229. 229.Strauss, S. H.; Whitmire, K. H.; Shriver, D. F., Rhodium(I)-catalyzed decomposition of formic acid. J. Organomet. Chem. 1979, 174, C59-C62, DOI: 10.1016/S0022-328X(00)85605-3.

  230. 230.Huddle, B. P.; Whitmire, K., An improved Victor-Meyer apparatus. J. Chem. Ed. 1977, 54, 261, DOI: 10.1021/ed054p261.