1. (1)M. J. McClain; A. E. Schlather; E. Ringe; N. S. King; L. Liu;A.  Manjavacas; M. W.Knight; I.Kumar; K. H. Whitmire H. O. Everitt; P. Nordlander; N. J. Halas, Aluminum Nanocrystals. Nano Lett. 2015, 15, 2751-2755; 10.1021/acs.nanolett.5b00614.

  2. (2)I. Kumar; P.Bhattacharya; K. H.  Whitmire, Structural diversity in phenyl bismuth(III) bis(carboxylate) complexes. J. Organomet. Chem. 2015, 794, 153-167; 10.1016/j.jorganchem.2015.06.023.

  3. (3)I. Kumar; P. Andrews; K. H. Whitmire, The Unexpected Isolation of Bismuth Tris(carboxylate) Hydrates: Syntheses and Structures of [Bi(Hsal)3(H2O)] and [Bi(Hanth)3(H2O)] (H2sal = 2-OH-C6H4CO2H, Hanth = 2-NH2-C6H4CO2H). Eur. J. Inorg. Chem. 2015, 2015 (4), 605-608; 10.1002/ejic.201403019

  4. (4)Davidovich, R. L.; Marinin, D. V.; Stavila, V.; Whitmire, K. H., Structural chemistry of fluoride and oxofluoride complexes of titanium(IV). Coord. Chem. Rev. 2015, 299, 61-82; 10.1016/j.ccr.2015.04.002.

  5. (5)I. Kumar; P. Bhattacharya; K. H. Whitmire, Facile One-Pot Synthesis of Triphenylbismuth(V) Bis(carboxylate) Complexes, Organometallics 2014, 33, 2906-2909, 10.1021/om500337z.

  6. (6)T. D. Boyd; I. Kumar; E. E. Wagner; K. H. Whitmire, Synthesis and structural studies of the simplest bismuth(III) oxo-salicylate complex: [Bi43-O)2(HO-2-C6H4CO2)8]·2Solv (Solv = MeCN or MeNO2), Chem. Commun. 2014, 50, 3556-3559, 10.1039/c4cc00056k.

  7. (7)R. L. Davidovich; D. V. Marinin; V. Stavila; K. H. Whitmire, Stereochemistry of fluoride and mixed-ligand fluoride complexes of zirconium and hafnium, Coord. Chem. Rev. 2013, 257, 3074-3088, 10.1016/j.ccr.2013.06.016.

  8. (8)T. Ould-Ely; D. Prieto-Centurion; I. Rusakova; K. H. Whitmire, Wet chemical synthesis and characterization of polypodal In2O3 nanoparticles, CrystEngComm 2013, 15, 6918-6922, 10.1039/c3ce41264d.

  9. (9)S. R. Walsh; I. Rusakova; K. Whitmire, H., Rock Salt vs. Wurtzite Phases of Co1-xMnxO: Control of Crystal Lattice and Morphology at the Nanoscale, CrystEngComm 2013, 15, 775 - 784, DOI:10.1039/c2ce26440d.

  10. (10)Colson, A. C.; Chen, C.-W.; Morosan, E.; Whitmire, K. H., Synthesis of Phase-Pure Ferromagnetic Fe3P Films from Single-Source Molecular Precursors. Adv. Func. Mater. 2011, accepted, http://dx.doi.org/10.1002/adfm.201102386DOI: . 10.1002/adfm.201102386

  11. (11)Mandal, T.; Piburn, G.; Stavila, V.; Rusakova, I.; Ould-Ely, T.; Colson, A. C.; Whitmire, K. H., New Mixed Ligand Single-Source Precursors for PbS Nanoparticles and Their Solvothermal Decomposition to Anisotropic Nano- And Microstructures. Chem. Mater. 2011, 23, 4158-4169.

  12. (12)Colson, A. C.; Whitmire, K. H., Synthesis of Fe2-xMnxP Nanoparticles from Single-Source Molecular Precursors. Chem. Mater. 2011, 23, 3731-3739. http://pubs.acs.org/doi/abs/10.1021/cm201435b

  13. (13)Whitmire, K. H., Molecular donuts and donut holes. Science 2010, 327, 38-39.

  14. (14)Stavila, V.; Whitmire, K. H., (N,N-dimethylformamide-κ,O)bis(3-hydroxypicolinate-κ2N,O)phenylbismuth(III). Acta Crystallogr., Sect. E Struct. Rep. Online 2010, E66, m1547-m1548.

  15. (15)Stavila, V.; Whitmire, K. H., Hexaaquacobalt(II) and hexaaquanickel(II) pyridine-2,6-dicarboxylatobismuth(III) dihydrates. Acta Cryst. 2010, C67, m65-m68.

  16. (16)Davidovich, R. L.; Stavila, V.; Whitmire, K. H., Stereochemistry of lead(II) complexes containing sulfur and selenium donor atom ligands. Coord. Chem. Rev. 2010, 254, 2193-2226.

  17. (17)Colson, A. C.; Whitmire, K. H., Synthesis, Characterization, and Reactivity of the Heterometallic Dinuclear μ-PH2 and μ-PPhH Complexes FeMn(CO)8(μ-PH2) and FeMn(CO)8(μ-PPhH). Organometallics 2010, 29, 4611-4618.

  18. (18)Bochmann, M.; Brookhart, M.; Gladysz, J. A.; Lichtenberger, D. L.; Liebeskind, L. S.; Marks, T. J.; Schrock, R. R.; Sweigart, D. A.; Whitmire, K. H., Dedication to the Special Volume for Dietmar Seyferth. Organometallics 2010, 29, 4647.

  19. (19)Stavila, V.; Whitmire, K. H.; Rusakova, I., Synthesis of Bi2S3 Nanostructures from Bismuth(III) Thiourea and Thiosemicarbazide Complexes. Chem. Mater. 2009, 21, 5456-5465.

  20. (20)Stavila, V.; Thurston, J. H.; Whitmire, K. H. "Selective Arylation Reactions of Bismuth-Transition Metal Salicylate Complexes," Inorg. Chem. 2009, 48, 6945-6951.

  21. (21)Levin, C. S.; Hofmann, C.; Ali, T. A.; Kelly, A. T.; Morosan, E.; Nordlander, P.; Whitmire, K. H.; Halas, N. J. "Magnetic-Plasmonic Core-Shell Nanoparticles," ACS Nano 2009, 3, 1379-1388.

  22. (22) Hofmann, C.; Thurston, J. H.; Hartman, K. B.; Alemany, L. B.; Whitmire, K. H. "New polyoxomolybdenum coordination compounds: Synthesis and characterization of mixed-valent Mo6O13(Hsal)2(sal)2(acac)2 and homovalent Mo4O10(acac)4 (Hsal- = 2-HO-C6H4CO2-, sal2- = 2-O-C6H4CO22-)," Inorg. Chim. Acta 2009, 362, 1665-1671.

  23. (23)Davidovich, R. L.; Stavila, V.; Marinin, D. V.; Voit, E. I.; Whitmire, K. H. "Stereochemistry of lead(II) complexes with oxygen donor ligands," Coord. Chem. Rev. 2009, 253, 1316-1352.

  24. (24)Machnikova, E.; Whitmire, K. H.; Hackerman, N. "Corrosion inhibition of carbon steel in hydrochloric acid by furan derivatives," Electrochim. Acta 2008, 53, 6024-6032.

  25. (25) Hofmann, C.; Rusakova, I.; Ould-Ely, T.; Prieto-Centurión, D.; Hartman, K. B.; Kelly, A. T.; Lüttge, A.; Whitmire, K. H. "Shape control of new FexO-Fe3O4 and Fe1-yMnyO-Fe3-z-Mn2O4 nanostructures," Adv. Func. Mater. 2008, 18, 1661-1667.

  26. (26) Zhao, B.-J.; Shine, H. J.; Marx, J. N.; Hofmann, C.; Whitmire, K. H. "Addition of the Phenoxathiin Cation Radical to Alkenes and Nonconjugated Dienes. Formation of (E)- and (Z)-(10-Phenoxathiiniumyl)alkenes and (E)- and (Z)-(10-Phenoxathiiniumyl)dienes on Basic Alumina," J. Org. Chem. 2007, 72, 6154-6161.

  27. (27) Stavila, V.; Thurston, J. H.; Prieto-Centurion, D.; Whitmire, K. H. "A new methodology for synthesis of aryl bismuth compounds: arylation of bismuth(III) carboxylates by sodium tetraarylborate salts," Organometallics 2007, 26, 6864-6866.

  28. (28) Stavila, V.; Fettinger, J. C.; Whitmire, K. H. "Synthesis and Characterization of New Phenylbis(salicylato)bismuth(III) Complexes," Organometallics 2007, 26, 3321-3328.

  29. (29) Shamsuddin, S.; Ali, M. S.; Whitmire, K. H.; Khokhar, A. R. "Synthesis characterization and X-ray crystal structures of cis-1,4-diaminocyclohexaneplatinum(II) nucleobase adducts," Polyhedron 2007, 26, 637-644.

  30. (30) Rusakova, I.; Ould-Ely, T.; Hofmann, C.; Prieto-Centurion, D.; Levin, C. S.;Halas, N. J.; Luettge, A.; Whitmire, K. H. "Nanoparticle Shape Conservation in the Conversion of MnO Nanocrosses into Mn3O4," Chem. Mater. 2007, 19, 1369-1375.

  31. (31) Kelly, A. T.; Rusakova, I.; Ould-Ely, T.; Hofmann, C.; Luettge, A.; Whitmire, K. H. "Iron Phosphide Nanostructures Produced from a Single-Source Organometallic Precursor: Nanorods, Bundles, Crosses, and Spherulites," Nano Letters 2007, 7, 2920-2925.

  32. (32) Zhao, B.-J.; Shine, H.; Marx, J.; Kelly, A.; Hofmann, C.; Whitmire, K. "Addition of thianthrene cation radical to non-conjugated dienes-Part I: Addition to one double bond," J. Sulfur Chem. 2006, 27, 127-138.

  33. (33) Zhao, B.-J.; Shine, H.; Marx, J.; Kelly, A.; Hofmann, C.; Ould-Ely, T.; Whitmire, K. "Addition of thianthrene cation radical to non-conjugated dienes-Part II: Addition to two double bonds," J. Sulfur Chem. 2006, 27, 139-147.

  34. (34) Whitmire, K., H.; Kelly, A. T.; Hofmann, C. In Comprehensive Organometallic Chemistry III; Crabtree, R. H., Mingos, D. M. P., Eds.; Elsevier: Oxford, 2006; Vol. 6, p 1 - 76.

  35. (35) Whitmire, K., H. In Comprehensive Organometallic Chemistry III; Crabtree, R. H., Mingos, D. M. P., Eds.; Elsevier: Oxford, 2006; Vol. 3, p 343 - 408.

  36. (36) Stavila, V.; Davidovich, R. L.; Gulea, A.; Whitmire, K. H. "Bismuth(III) complexes with aminopolycarboxylate and polyaminopolycarboxylate ligands: Chemistry and structure," Coord. Chem. Rev. 2006, 250, 2782-2810.

  37. (37) Ould-Ely, T.; Prieto-Centurion, D.; Kumar, A.; Guo, W.; Knowles, W. V.; Asokan, S.; Wong, M. S.; Rusakova, I.; Luettge, A.; Whitmire, K. H. "Manganese(II) Oxide Nanohexapods: Insight into Controlling the Form of Nanocrystals," Chem. Mater. 2006, 18, 1821-1829.

  38. (38) Ali, M. S.; Longoria, E.; Ely, T. O.; Whitmire, K. H.; Khokhar, A. R. "Homopiperazine Pt(II) adducts with DNA bases and nucleosides: Crystal structure of [PtII(homopiperazine)(9-ethylguanine)2](NO3)2," Polyhedron 2006, 25, 2065-2071.

  39. (39) Whitmire, K., H. In Encyclopedia of Inorganic Chemistry; 2nd ed.; King, R. B., Ed.; Wiley Interscience: New York, NY, 2005; Vol. 1, p 404-425.

  40. (40)Whitmire, K., H. In Encyclopedia of Inorganic Chemistry; 2nd ed.; King, R. B., Ed.; Wiley Interscience: New York, NY, 2005; Vol. 1, p 425-440.

  41. (41)Shine, H. J.; Rangappa, P.; Marx, J. N.; Shelly, D. C.; Ould-Ely, T.; Whitmire, K. H. "Adducts of Thianthrene- and Phenoxathiin Cation Radical Salts with Symmetrical Alkynes. Structure and Formation of Cumulenes on Alumina Leading to a-Diketones, α-Hydroxyalkynes, and α-Acetamidoalkynes," J. Org. Chem. 2005, 70, 3877-3883.

  42. (42)Seyferth, D.; Marks, T. J.; Liebeskind, L. S.; Sweigart, D. A.; Whitmire, K. H. "A Great Day for Organometallic Chemistry," Organometallics 2005, 24, 6073.

  43. (43)Rangappa, P.; Shine, H. J.; Marx, J. N.; Ould-Ely, T.; Kelly, A. T.; Whitmire, K. H. "Adducts of Thianthrene- and Phenoxathiin Cation Radical Tetrafluoroborates to 1-Alkynes. Structures and Formation of 1-(5-Thianthreniumyl)- and 1-(10- Phenoxathiiniumyl)alkynes on Alumina Leading to a-Ketoylides and a-Ketols," J. Org. Chem. 2005, 70, 9764-9770.

  44. (44)Ould-Ely, T.; Thurston, J. H.; Whitmire, K. H. "Heterobimetallic bismuth transition metal coordination complexes as single-source molecular precursors for the formation of advanced oxide materials," Comptes Rend. Chim. 2005, 8, 1906-1921.

  45. (45)Ould-Ely, T.; Thurston, J. H.; Kumar, A.; Respaud, M.; Guo, W.; Weidenthaler, C.; Whitmire, K. H. "Wet-Chemistry Synthesis of Nickel-Bismuth Bimetallic Nanoparticles and Nanowires," Chem. Mater. 2005, 17, 4750-4754.

  46. (46)Escovar, R. M.; Thurston, J. H.; Ould-Ely, T.; Kumar, A.; Whitmire, K. H. "Synthesis and characterization of new mono-, di-, and trinuclear copper(II) triethanolamine-carboxylate complexes," Z. Anorg. Allg. Chem. 2005, 631, 2867-2876.

  47. (47)Ali, M. S.; Ali Khan, S. R.; Ojima, H.; Guzman, I. Y.; Whitmire, K. H.; Siddik, Z. H.; Khokhar, A. R. "Model platinum nucleobase and nucleoside complexes and antitumor activity: X-ray crystal structure of [PtIV(trans-1R 2Rdiaminocyclohexane) trans(acetate)2(9-ethylguanine)Cl]NO3.H2O," J. Inorg. Biochem. 2005, 99, 795-804.

  48. (48)Thurston, J., H.; Trahan, D.; Ould-Ely, T.; Whitmire Kenton, H. "Toward a general strategy for the synthesis of heterobimetallic coordination complexes for use as precursors to metal oxide materials: synthesis, characterization, and thermal decomposition of Bi2(Hsal)6.M(acac)3 (M = Al, Co, V, Fe, Cr)," Inorg. Chem. 2004, 43, 3299-305.

  49. (49)Thurston, J., H.; Tang, C., G. Z.; Trahan, D., W.; Whitmire, K., H. "Toward rational control of metal stoichiometry in heterobimetallic coordination complexes: synthesis and characterization of Pb(Hsal)2{Cu(salen*)}2, [Pb(NO3){Cu(salen*)}2](NO3), Pb(OAc)2(Cu(salen*)), and [Pb(OAc)(Ni(salen*))2](OAc)," Inorg. Chem. 2004, 43, 2708-13.

  50. (50)Thurston, J., H.; Kumar, A.; Hofmann, C.; Whitmire, K., H. "Heterobimetallic Bi(III)-Ti(IV) coordination complexes: synthesis and solid-state structures of BiTi4(sal)6(μ-OiPr)3(OiPr)4, and the cyclic isomers Bi4Ti4(sal)10(μ-OiPr)4(OiPr)4 and Bi8Ti8(sal)20(μ-OiPr)8(OiPr)8," Inorg. Chem. 2004, 43, 8427-36.

  51. (51)Shine, H. J.; Zhao, B.-J.; Marx, J. N.; Ould-Ely, T.; Whitmire, K. H. "Decomposition of Alkene Adducts of Thianthrene Cation Radical in Nitrile Solvents. Formation of Alkyl-2-oxazolines and a New Class of Four-Component Products: 5-[(1-Alkoxyalkylidene)ammonio]alkylthianthrenium Diperchlorates," J. Org. CHem. 2004, 69, 9255-9261.

  52. (52)Umezawa-Vizzini, K.; Guzman-Jimenez, I. Y.; Whitmire, K. H.; Lee, T. R. "Synthesis, Characterization, and Thermal Stability of (η61- C6H5CH2CH2PR2)Ru(CH3)2 (R = Cy, Ph, Et)," Organometallics 2003, 22, 3059-3065.

  53. (53)Thurston, J. H.; Whitmire, K. H. "Molecular Precursors for Ferroelectric Materials: Synthesis and Characterization of Bi2M2(μ-O)(sal)4(Hsal)4(OEt)2 and BiM4(μ-O)4(sal)4(Hsal)3(OiPr)4 (sal = O2CC6H4O, Hsal = O2CC6H4OH) (M = Nb, Ta)," Inorg. Chem. 2003, 42, 2014-2023.

  54. (54)Thurston, J. H.; Ely, T. O.; Trahan, D.; Whitmire, K. H. "Nanostructured Bimetallic Oxide Ion-Conducting Ceramics from Single-Source Molecular Precursors," Chem. Mater. 2003, 15, 4407-4416.

  55. (55)Shine, H. J.; Zhao, B.; Qian, D.-Q.; Marx, J. N.; Guzman-Jimenez, I. Y.; Thurston, J. H.; Ould-Ely, T.; Whitmire, K. H. "Adducts of Phenoxathiin and Thianthrene Cation Radicals with Alkenes and Cycloalkenes," J. Org. Chem. 2003, 68, 8910-8917.

  56. (56)Qian, D.-Q.; Shine, H. J.; Thurston, J. H.; Whitmire, K. H. "Nucleophilic reactions of 5-(aryl)thianthrenium bromides with sodium aryloxides," J. Phys. Org. Chem. 2003, 16, 142-147.

  57. (57)Mukhopadhyay, U.; Thurston, J.; Whitmire, K. H.; Siddik, Z. H.; Khokhar, A. R. "Preparation, characterization, and antitumor activity of new cisplatin analogues with 1-methyl-4-(methylamino)piperidine: Crystal structure of [PtII(1-methyl-4-(methylamino)piperidine)(oxalate)]," J. Inorg. Biochem. 2003, 94, 179-185.

  58. (58)Guzman-Jimenez, I. Y.; Van Hal, J. W.; Whitmire, K. H. "Metal Cluster Catalysis: A Kinetic and Mechanistic Study of the Carbonylation of Methanol to Give Methyl Formate as Catalyzed by [Et4N]2[Fe3(CO)9E] (E = S, Se, Te)," Organometallics 2003, 22, 1914-1922.

  59. (59)Bachman, R. E.; Whitmire, K. H.; Thurston, J. H.; Gulea, A.; Stavila, O.; Stavila, V. "Bismuth ladder polymers: structural and thermal studies of [Bi(OCH2CH2)3N]n and [(BixTb1-x(O2C2H2)3N.2H2O]n," Inorg. Chim.Acta 2003, 346, 249-255.

  60. (60)Xu, L.; Whitmire, K. H. "Hybrid Metal Carbonyl-Oxide Clusters: Synthesis and Structure of [Et4N]2[(OC)5WSbW3(CO)93-OMe)23-O)WO2(OR)] (R = Me, H)," Organometallics 2002, 21, 2581-2583.

  61. (61)Whitmire, K. H.; Derringer, D. R.; Kongkasuwan, K. R. "Tris[bis(diphenylphosphino)methane-k2P,P']rhenium(I) perrhenate," Acta Cryst. 2002, E58, m363-m365.

  62. (62)Thurston, J. H.; Whitmire, K. H. "Heterobimetallic Bismuth-Transition Metal Salicylate Complexes as Molecular Precursors for Ferroelectric Materials. Synthesis and Structure of Bi2M2(sal)4(Hsal)4(OR)4 (M = Nb, Ta; R = CH2CH3, CH(CH3)2), Bi2Ti3(sal)8(Hsal)2, and Bi2Ti4(OiPr)(sal)10(Hsal) (sal = O2CC6H4-2-O; Hsal = O2CC6H4-2-OH)," Inorg. Chem. 2002, 41, 4194-4205.

  63. (63)Thurston, J. H.; Marlier, E. M.; Whitmire, K. H. "Towards a molecular model for bismuth(III) subsalicylate. Synthesis and solid-state structure of [Bi(Hsal)3(bipy)(C7H8)]2 and [Bi(Hsal)(sal)(1,10-phenanthroline)(C7H8)]2," J. Chem. Soc., Chem. Comm. 2002, 2834-2835.

  64. (64)Qian, D.-Q.; Shine, H. J.; Guzman-Jimenez, I. Y.; Thurston, J. H.; Whitmire, K. H. "Mono- and Bisadducts from the Addition of Thianthrene Cation Radical Salts to Cycloalkenes and Alkenes," J. Org. Chem. 2002, 67, 4030-4039.

  65. (65)Qian, D.-Q.; Liu, B.; Shine, H. J.; Guzman-Jimenez, I. Y.; Whitmire, K. H. "Ring-opening reactions of 5-(aryl)thianthrenium bromides with aryl thiolates," J. Phys. Org. Chem. 2002, 15, 139-147.

  66. (66) Mukhopadhyay, U.; Thurston, J. H.; Whitmire, K. H.; Khokhar, A. R. "Synthesis and characterization of cis-bis-heptamethyleneimine platinum(II) dicarboxylate complexes: crystal structure of cis-[Pt(heptamethyleneimine)2(malonate)].H2O," Polyhedron 2002, 21, 2369-2374.

  67. (67)Ali, M. S.; Thurston, J. H.; Whitmire, K. H.; Khokhar, A. R. "Synthesis and characterization of platinum(II) and (IV) complexes containing hexamethyleneimine ligand: crystal structure of [PtII(hexamethyleneimine)2(cyclobutanedicarboxylato)].H2O," Polyhedron 2002, 21, 2659-2665.

  68. (68)Ali, M. S.; Mukhopadhyay, U.; Shirvani, S. M.; Thurston, J.; Whitmire, K. H.; Khokhar, A. R. "Homopiperazine platinum(II) complexes containing substituted sulfide groups: crystal structure of [PtII(homopiperazine)(diphenylsulfide)Cl]NO3," Polyhedron 2002, 21, 125-131.

  69. (69)Litosh, V. A.; Saini, R. K.; Guzman-Jimenez, I. Y.; Whitmire, K. H.; Billups, W. E. "Reactions of Cycloproparenes with Metal Carbenes," Org. Lett. 2001, 3, 65-66.

  70. (70)Lee, W. K.; Liu, B.; Park, C. W.; Shine, H. J.; Guzman-Jimenez, I. Y.; Whitmire, K. H. "Addition of Thianthrene Cation Radical to Cycloalkenes. An Unexpected Monoadduct. [ Erratum for Volume 64, 1999 ]," J. Org. Chem. 2001, 66, 1064.

  71. (71)Guzman-Jimenez, I. Y.; Whitmire, K. H.; Umezama-Vizzini, K.; Colorado, R.; Do, J.; Jacobson, A.; Lee, T. R.; Hong, S.; Mirkin, C. A. "Self-assembly of organometallic clusters onto the surface of gold," Thin Solid Films 2001, 401, 131-137.

  72. (72)Ali, M. S.; Powers, C. A.; Whitmire, K. H.; Guzman-Jimenez, I.; Khokhar, A. R. "Synthesis, characterization, and representative crystal structure of lipophilic platinumII (homopiperazine)carboxylate complexes," J. Coord. Chem. 2001, 52, 273-287.

  73. (73)Whitmire, K. H.; Hoppe, S.; Sydora, O.; Jolas, J. L.; Jones, C. M. "Oligomerization and Oxide Formation in Bismuth Aryl Alkoxides: Synthesis and Characterization of Bi44-O)(μ-OC6F5)63-OBi(μ-OC6F5)3}2(C6H5CH3), Bi84-O)23-O)2(μ-OC6F5)16, Bi63-O)43-OC6F5){μ3-OBi(OC6F5)4}3, NaBi43-O)2(OC6F5)9(THF)2, and Na2Bi43-O)2(OC6F5)10(THF)2," Inorg. Chem. 2000, 39, 85-97.

  74. (74)Whitmire, K. H.; Guzman-Jimenez, I. Y.; Saillard, J.-Y.; Kahlal, S. "Synthesis, characterization, structural and theoretical analysis of a series of electron deficient, monomeric thallium iron carbonylate isostructural and isolobal to diiron nonacarbonyl," J. Organomet. Chem. 2000, 614-615, 243-254.

  75. (75)Khan, S. R. A.; Guzman-Jimenez, I.; Whitmire, K. H.; Khokhar, A. R. "Synthesis and characterization of platinum(II) complexes with 3-methylpiperidine: crystal and molecular structure of [Pt(3-methylpiperidine)2(malonato)].H2O," Polyhedron 2000, 19, 983-989.

  76. (76)Engel, P. S.; Pan, L.; Whitmire, K. H.; Guzman-Jimenez, I.; Willcott, M. R.; Smith, W. B. "Mechanistic Studies of a Linear Trisazoalkane, a New Azimine, and a Bicyclic Triaziridine. Azoalkane Homolysis into Seven Fragments," J. Org. Chem. 2000, 65, 1016-1021.

  77. (77)Ali Khan, S. R.; Huang, S.; Shamsuddin, S.; Inutsuka, S.; Whitmire, K. H.; Siddik, Z. H.; Khokhar, A. R. A. R. "Synthesis, characterization and cytotoxicity of new platinum(IV) axial carboxylate complexes: crystal structure of potential antitumor agent [PtIV(trans-1R,2R-diaminocyclohexane)trans(acetate)2Cl2]," Bioorg. Med. Chem. 2000, 8, 515-521.

  78. (78)Whitmire, K. H.; Hutchison, J. C.; Gardberg, A.; Edwards, C. "Triethanolamine complexes of copper," Inorg. Chim. Acta 1999, 294, 153-162.

  79. (79)Stark, J. L.; Harms, B.; Guzman-Jimenez, I.; Whitmire, K. H.; Gautier, R.; Halet, J.-F.; Saillard, J.-Y. "Different Ways To Distort a Tetracapped Tetrahedron on Route to Forming an E4M4 Cubane: The Case of [E4(Pd(PPh2Me)2)4][Ph2EX2]2 (E = Sb, X = Cl; E = Bi, X = Br)," J. Am. Chem. Soc. 1999, 121, 4409-4418.

  80. (80)Lee, W. K.; Liu, B.; Park, C. W.; Shine, H. J.; Guzman-Jimenez, I. Y.; Whitmire, K. H. "Addition of thianthrene cation radical to cycloalkenes. An unexpected monoadduct," J. Org. Chem. 1999, 64, 9206-9210.

  81. (81)Ali, M. S.; Whitmire, K. H.; Toyomasu, T.; Siddik, Z. H.; Khokhar, A. R. "Preparation, characterization, and antitumor activity of new cisplatin analogs with homopiperazines: crystal structure of [PtII(1-methylhomopiperazine)(methylmalonato)].2H2O," J. Inorg. Biochem. 1999, 77, 231-238.

  82. (82)Zouchoune, B.; Ogliaro, F.; Halet, J.-F.; Saillard, J.-Y.; Eveland, J. R.; Whitmire, K. H. "Bonding Analysis in Inorganic Transition-Metal Cubic Clusters. 3. Metal-Centered Tetracapped M95-E)4Ln Species with a Tetragonal Distortion," Inorg. Chem. 1998, 37, 865-875.

  83. (83)Whitmire, K. H. In The Chemistry of Arsenic, Antimony and Bismuth; Norman, N. C., Ed.; Blackie Academic and Professional Books: Glasgow, 1998, p 345-402.

  84. (84)Whitmire, K. H. "Main group-transition metal cluster compounds of the group 15 elements," Adv. Organomet. Chem. 1998, 42, 1-145.

  85. (85)van Hal, J. W.; Whitmire, K. H. "Site-directed alkylation of [EFe3(CO)9]2- (E = S, Se, Te) mediated by the chalcogenide. Synthesis, spectroscopic characterization, and reactivity of [PPN][MeFe3(CO)9E] (E = Se, Te)," Organometallics 1998, 17, 5197-5201.

  86. (86)van Hal, J. W.; Stark, J. L.; Whitmire, K. H. "Hydride abstraction from [PPN]2[HSb{Fe(CO)4}3] by alkyl iodides. Synthesis and characterization of [PPN][Sb(Me)I{Fe(CO)4}2]," J. Organomet. Chem. 1998, 557, 163-167.

  87. (87)Shamsuddin, S.; Santillan, C. C.; Stark, J. L.; Whitmire, K. H.; Siddik, Z. H.; Khokhar, A. R. "Synthesis, characterization, and antitumor activity of new platinum(IV) trans-carboxylate complexes: crystal structure of [Pt(cis-1,4-DACH)trans-(acetate)2Cl2]," J. Inorg. Biochem. 1998, 71, 29-35.

  88. (88)Hoppe, S.; Whitmire, K. H. "Synthesis and Structure of Pentavalent Bismuth(V) Alkoxides and Ligand Redistribution Equilibria in Solution," Organometallics 1998, 17, 1347-1354.

  89. (89)Engel, P. S.; Duan, S.; Whitmire, K. H. "Structure and Stability of an Azoalkane-Iodine Complex," J. Org. Chem. 1998, 63, 5666-5667.

  90. (90)Whitmire, K. H.; Hutchison, J. C.; Burkart, M. D.; Lee, J.; Ezenwa, S.; McKnight, A. L.; Jones, C. M.; Bachman, R. E. "Main group-transition metal carbonyl complexes," Inorg. Synth. 1997, 31, 220-228.

  91. (91)van Hal, J. W.; Alemany, L. B.; Whitmire, K. H. "Solution Dynamics of Thallium-Metal Carbonyl Compounds Using 205Tl NMR Spectroscopy," Inorg. Chem. 1997, 36, 3152-3159.

  92. (92)Shamsuddin, S.; van Hal, J. W.; Stark, J. L.; Whitmire, K. H.; Khokhar, A. R. "Synthesis and Characterization of Novel Axial Dichloroplatinum(IV) Cisplatin Analogs: Crystal Structure of an Axial Dichloro Complex [Pt(cis-1,4- DACH)(trans-Cl2)(CBDCA)].1/2MeOH," Inorg. Chem. 1997, 36, 5969-5971.

  93. (93)Jolas, J. L.; Hoppe, S.; Whitmire, K. H. "Oligomerization and Oxide Formation in Bismuth Aryloxides: Synthesis, Characterization, and Structures of [NaBi(OC6F5)4(THF)]inf and Na4Bi26-O)(OC6F5)8(THF)4," Inorg. Chem. 1997, 36, 3335-3340.

  94. (94)Eveland, J. R.; Whitmire, K. H. "Synthesis and characterization of the carbide cubane cluster [Fe3(CO)9Te43-CTeBr4)] with an unusual tetrahedral CTe4 unit," Angew. Chem., Int. Ed. Eng. 1997, 36, 1193-1194.

  95. (95)Eveland, J. R.; Saillard, J.-Y.; Whitmire, K. H. "Effect of Hybridization on Structure and Bonding of Cluster Compounds Possessing a Square-Pyramidal Fe3(CO)9E2 Core (E = Element of Group 15 or 16)," Inorg. Chem. 1997, 36, 330-334.

  96. (96)Eveland, J. R.; Saillard, J.-Y.; Whitmire, K. H. "Halide Ion Addition to Bismuth-Containing Iron Carbonyl Compounds: Synthesis and Characterization of the Two Bridged-Butterfly Cluster Compounds [Et4N][(μ-H)Fe2(CO)6Bi2{μ-Fe(CO)4}] and [{PhCH2NMe3}{(μ-H)Fe2(CO)6Bi2(μ-Cl)2}]n and Stabilization of Reduced-Hypervalent Bismuth Centers by Coordination to a Metal Center in [PhCH2NMe3]3[Bi3Cl4(μ-Cl)4{Fe(CO)3}]," Inorg. Chem. 1997, 36, 4387-4396.

  97. (97)Das, G.; Shukla, R.; Mandal, S.; Singh, R.; Bharadwaj, P. K.; van Hal, J.; Whitmire, K. H. "Syntheses and X-Ray Structures of Mixed-Ligand Salicylaldehyde Complexes of Mn(III), Fe(III), and Cu(II) Ions: Reactivity of the Mn(III) Complex Toward Primary Monoamines and Catalytic Epoxidation of Olefins by the Cu(II) Complex," Inorg. Chem. 1997, 36, 323-329.

  98. (98)Eveland, J. R.; Whitmire, K. H. "Synthesis and characterization of the novel iron carbonyl tellurium chloride cluster [Fe2(CO)6(μ-Cl)(μ-TeCl)2]222μ2-Te2Cl10], and its decomposition to the Zintl ion complex [Fe2(CO)6222-Te4)(μ-TeCl2)]," Angew. Chem. Int. Ed. Eng. 1996, 35, 741-3.

  99. (99)Eveland, J. R.; Whitmire, K. H. "Complexes of bismuth(III) chloride with oxygen donor ligands. Structural characterization of BiCl3.3THF, BiCl3.diglyme and BiCl3.diethylcarbitol," Inorg. Chim. Acta 1996, 249, 41-46.

  100. (100)Whitmire, K. H. "Perspectives on bismuth alkoxide chemistry and its relation to bismuth-oxide-based materials and catalysts," Chemtracts: Inorg. Chem. 1995, 7, 167-181.

  101. (101)van Hal, J. W.; Whitmire, K. H.; Zouchoune, B.; Halet, J.-F.; Saillard, J.-Y. "Synthesis, Characterization, and Molecular Orbital Analysis of [Et4N]2[(OC)5MoAsMo3(CO)93-OR)3Mo(CO)3] (R = Me, Et). X-ray Structure of [Et4N]2[(OC)5MoAsMo3(CO)93-OMe)3Mo(CO)3].0.6thf," Inorg. Chem. 1995, 34, 5455-60.

  102. (102)Bachman, R. E.; Whitmire, K. H.; van Hal, J. "Effect of Charge on Structure: Stepwise Protonation of [EFe3(CO)9]2- (E = Se, Te) and Isolation of a Novel Mixed-Metal Cluster [TeFe3(CO)9(μ-CuCl)]2-," Organometallics 1995, 14, 1792-801.

  103. (103)Bachman, R. E.; Whitmire, K. H. "Synthesis and Structure of Carbonyl-Metalated Organobismuth Complexes," Inorg. Chem. 1995, 34, 1542-51.

  104. (104)Bachman, R. E.; Miller, S. K.; Whitmire, K. H. "Structural and Reactivity Consequences of the Presence of Lone Pairs in Main-Group-Transition-Metal Cluster Compounds: Conversion of [HAs{Fe(CO)4}3]2- into [Fe3(CO)93-AsFe(CO)4}2]2," Organometallics 1995, 14, 796-803.

  105. (105)Bachman, R. E.; Maughon, B. R.; McCord, D. J.; Whitmire, K. H.; Billups, W. E. "(Bromodichloromethyl)phenylmercury," Acta Cryst. 1995, C51, 2033-5.

  106. (106)Whitmire, K. H.; Eveland, J. R. "Structural characterization of two large bismuthcobalt carbonyl clusters: (PPN)2[Bi4Co9(CO)8(μ-CO)8].2THF and (PPN)2[Bi8Co14(CO)12(μ-CO)8].1.08THF," J. Chem. Soc., Chem. Comm. 1994, 1335-6.

  107. (107)Whitmire, K. H. In Encyclopedia of Inorganic Chemistry; King, R. B., Ed.; John Wiley: New York, 1994; Vol. vol. 1, p 292-300.

  108. (108)Whitmire, K. H. In Encyclopedia of Inorganic Chemistry; King, R. B., Ed.; John Wiley: New York, 1994; Vol. vol. 1, p 280-291.

  109. (109)Shukla, R.; Bharadwaj, P. K.; Van Hal, J.; Whitmire, K. H. "Mononuclear manganese(III) complexes with imine/amine and phenolate ligation: x-ray structural, spectroscopic and electrochemical studies," Polyhedron 1994, 13, 2387-94.

  110. (110)Kahlal, S.; Halet, J.-F.; Saillard, J.-Y.; Whitmire, K. H. "Bonding analysis of electron-rich bridged mixed main-group/transition metal tetrahedral M2E2 organometallic clusters," J. Organomet. Chem. 1994, 478, 1-8.

  111. (111)Engel, P. S.; Wu, A.; Whitmire, K. H. "1,2-Azoxy Rearrangement and Fragmentation of β-Azoxy Radicals," J. Am. Chem. Soc. 1994, 116, 4079-80.

  112. (112)Ciufolini, M. A.; Rivera-Fortin, M. A.; Zuzukin, V.; Whitmire, K. H. "Origin of Regioselectivity in Paterno-Buechi Reactions of Benzoquinones with Alkylidenecycloalkanes," J. Am. Chem. Soc. 1994, 116, 1272-7.

  113. (113)Bachman, R. E.; Whitmire, K. H. "The Synthesis and Characterization of a Series of Iron Carbonyl Clusters Containing Selenium and Tellurium," Inorg. Chem. 1994, 33, 2527-33.

  114. (114)Bachman, R. E.; Whitmire, K. H. "Molecular and crystal structure of [Et4N][Cl].2[Fe2(CO)6Te2]," J. Organomet. Chem. 1994, 479, 31-5.

  115. (115)Bachman, R. E.; Miller, S. K.; Whitmire, K. H. "Synthesis and Structure of an Anionic Arsenic Hydride Complex: [PPN]2[HAs{Fe(CO)4}3].0.5THF," Inorg. Chem. 1994, 33, 2075-6.

  116. (116)Jones, C. M.; Burkart, M. D.; Bachman, R. E.; Serra, D. L.; Hwu, S. J.; Whitmire, K. H. "Hypervalent bismuth alkoxide dimer complexes: syntheses, structures, and thermal decompositions of [Bi(OCH(CF3)2)2(μ-OCH(CF3)2)(THF)]2 and [Bi(OC6F5)2(μ-OC6F5)Xn]2.zY (X = Y = C7H8, n = 1, z = 1 or 2; X = THF, Y = C6H14, n = 2, z = 0 or 1)," Inorg. Chem. 1993, 32, 5136-44.

  117. (117)Cassidy, J. M.; Whitmire, K. H.; Kook, A. M. "Solution dynamics of tin and lead iron carbonyl compounds and the solid state structure of [Et4N]2[Sn{Fe2(CO)8}{Fe(CO)4}2]," J. Organomet. Chem. 1993, 456, 61-70.

  118. (118) Bartik, T.; Bartik, B.; Hanson, B. E.; Whitmire, K. H.; Guo, I. "Reactions of trisulfonated triphenylphosphine, TPPTS, with cobalt carbonyls in water," Inorg. Chem. 1993, 32, 5833-7.

  119. (119)Bachman, R. E.; Whitmire, K. H. "Reduction of tellurium by Na2[Fe(CO)4]: synthesis and reactivity of [PPN]2[Fe2(CO)6(Te2)2]," Organometallics 1993, 12, 1988-92.

  120. (120)Bachman, R. E.; Whitmire, K. H. "Bis[bis(triphenylphosphine)iminium] dodecacarbonylhexanickelate," Acta Cryst. 1993, C49, 1121-3.

  121. (121)Whitmire, K. H.; Jones, C. M.; Burkart, M. D.; Hutchison, J. C.; McKnight, A. "Aggregation and hydrolysis reactions of bismuth alkoxides," Mat. Res. Soc. Sym. Proc. 1992, 271, 149-54.

  122. (122)Whitmire, K. H.; Hutchison, J. C.; McKnight, A. L.; Jones, C. M. "Synthesis and structure of [Et2Bi(OAr)]n (Ar = C6F5, Ph): a new inorganic chain polymer," J. Chem. Soc., Chem. Comm. 1992, 1021-2.

  123. (123)Whitmire, K. H.; Cassidy, J. M. "Two New Crystal Morphologies for Tetraphenyldibismuthine, Bi2Ph4," Acta Cryst. 1992, C48, 917-919.

  124. (124)Long, G. J.; Grandjean, F.; Whitmire, K. H. "Moessbauer spectroscopic observation of ligand dynamics in [HFe(CO)4]- ions. Proof of a tunneling hydride ligand," Angew. Chem. 1992, 104, 891-3 (See also Angew. Chem., Int. Ed. Engl., 1992, 31(7), 884-6).

  125. (125)Jones, C. M.; Burkart, M. D.; Whitmire, K. H. "Dimeric alkoxido bismuth complexes with planar [Bi2(μ-OR)2] units. Synthesis and structure of [{Bi[OCH(CF3)2]3(THF)}2] and [Bi(OC6F5)3(C7H8)]2.2C7H8," Angew. Chem., Int. Ed. Engl. 1992, 31(4), 451-2.

  126. (126)Jones, C. M.; Burkart, M. D.; Whitmire, K. H. "Novel aryloxybismuth oxide clusters: x-ray crystal structures of Bi63-O)73-OC6F5){Bi(OC6F5)4}3(THF)2 and Bi63-O)73-OC6F5){Bi(OC6F5)4}.2C7H8 (THF = tetrahydrofuran)," J. Chem. Soc., Chem. Comm. 1992, 1638-9.

  127. (127)Jones, C. M.; Burkart, M. D.; Whitmire, K. H. "Dimeric alkoxido bismuth complexes with planar [Bi2(μ-OR)2] units. Synthesis and structure of [{Bi[OCH(CF3)2]3(THF)}2] and [Bi(OC6F5)3(C7H8)]2.2C7H8," Angew. Chem. 1992, 104, 466-7 (See also Angew. Chem., Int. Ed. Engl., 1992, 31(4), 451-2).

  128. (128)Cassidy, J. M.; Whitmire, K. H.; Long, G. J. "Structure and Moessbauer effect study of [Et4N]2[Fe2(CO)8]," J. Organomet. Chem. 1992, 427, 355-62.

  129. (129)Burgess, K.; Ohlmeyer, M. J.; Whitmire, K. H. "Stereochemically matched (and mismatched) bisphosphine ligands: DIOP-DIPAMP hybrids," Organometallics 1992, 11, 3588-600.

  130. (130)Bachman, R. E.; Whitmire, K. H.; Mandal, S.; Bharadwaj, P. K. "Dichlorotetrakis(pyridine)nickel(II)," Acta Cryst. 1992, C48, 1836-7.

  131. (131)Whitmire, K. H.; Roesky, H. W.; Brooker, S.; Sheldrick, G. M. "Carbon-fluorine bond activation in the reaction of bismuth trichloride with sodium 2,4,6-tris(trifluoromethyl)phenoxide," J. Organomet. Chem. 1991, 402, C4-C7.

  132. (132)Whitmire, K. H.; Labahn, D.; Roesky, H. W.; Noltemeyer, M.; Sheldrick, G. M. "Sterically crowded aryl bismuth compounds: synthesis and characterization of bis[2,4,6-tris(trifluoromethyl)phenyl] bismuth chloride and tris[2,4,6-tris(trifluoromethyl)phenyl] bismuth," J. Organomet. Chem. 1991, 402, 55-66.

  133. (133)Whitmire, K. H. "A Comparison of Bismuth- and Antimony-containing Transition Metal Cluster Complexes," J. Cluster Science 1991, 2, 231-258.

  134. (134)Cassidy, J. M.; Whitmire, K. H. "Syntheses and structures of the phenylbismuth/transition-metal carbonyl compounds [PPN][Ph2BiFe(CO)4], (Ph2Bi)2Fe(CO)4, [PhBiFe(CO)4]2 and Ph2BiMn(CO)5," Inorg. Chem. 1991, 30, 2788-95.

  135. (135)Cassidy, J. M.; Whitmire, K. H. "Structures of chlorotris(triphenylphosphine)cobalt and chlorotris(triphenylphosphine)nickel toluene solvate (1:1)," Acta Cryst. 1991, C47, 2094-8.

  136. (136)Brooker, S.; Edelmann, F. T.; Kottke, T.; Roesky, H. W.; Sheldrick, G. M.; Stalke, D.; Whitmire, K. H. "Comparison of the x-ray crystal structure of the sodium and potassium 2,4,6-tris(trifluoromethyl)phenoxides (RO-) and 2,4,6-tris(trifluoromethyl)benzenethiolates (RS-); [Na(OR)(thf)2]2, [K(OR)(thf)2(μ-thf)]2, [Na(SR)(thf)2.0.25thf]x and [K(SR)(thf)]x (thf = tetrahydrofuran)," J. Chem. Soc., Chem. Comm. 1991, 144-6.

  137. (137)Billups, W. E.; Lee, G. A.; Arney, B. E., Jr.; Whitmire, K. H. "1,3-Bridged cyclopropenes," J. Am. Chem. Soc. 1991, 113, 7980-4.

  138. (138)Albright, T. A.; Yee, K. A.; Saillard, J. Y.; Kahlal, S.; Halet, J. F.; Leigh, J. S.; Whitmire, K. H. "Capping considerations in main-group/transition-metal clusters: synthetic, structural, and theoretical discussions of [E2Co4(CO)10(μ-CO)-/2- (E = Sb, Bi)," Inorg. Chem. 1991, 30, 1179-90.

  139. (139)Stalke, D.; Whitmire, K. H. "Spectroscopic and structural characterization of 2,4,6-tris(trifluoromethyl)phenyllithium.Et2O: a dimer stabilized by lithium...fluorine contacts," J. Chem. Soc., Chem. Comm. 1990, 833-4.

  140. (140)Margrave, J. L.; Whitmire, K. H.; Hauge, R. H.; Norem, N. T. "Synthesis and characterization of bis(trifluoromethyl)gold mu-halide dimers: x-ray structural characterization of [Au(CF3)2(μ-I)]2," Inorg. Chem. 1990, 29, 3252-3.

  141. (141)Leigh, J. S.; Whitmire, K. H. "The structures of tetrakis(tetracarbonylcobaltio)tin and tetrakis(tetracarbonylcobaltio)lead," Acta Cryst. 1990, C46, 732-6.

  142. (142)Hanson, B. E.; Whitmire, K. H. "Exchange of axial and equatorial carbonyl groups in pentacoordinate metal carbonyls in the solid state. The variable temperature magic angle spinning carbon-13 NMR spectroscopy of iron pentacarbonyl, [Ph3PNPPh3][HFe(CO)4], and [NEt4][HFe(CO)4]," J. Am. Chem. Soc. 1990, 112, 974-7.

  143. (143)Cassidy, J. M.; Whitmire, K. H. "Structures of [(C2H5)4N]2[In2Fe6(CO)24] and [(C2H5)4N][(2,2'-bipyridine)InFe2(CO)8]," Acta Cryst. 1990, C46, 1781-5.

  144. (144)(126) Burgess, K.; Ohlmeyer, M. J.; Whitmire, K. H. "Stereochemical assignments via cyclic derivatives: a cautionary note," J. Org. Chem. 1990, 55, 1359-61.

  145. (145)Whitmire, K. H.; Shieh, M.; Cassidy, J. "Synthesis, characterization, and reactivity of iron carbonyl clusters containing bismuth or antimony. Crystal structures of isomorphous [Et4N][BiFe3Cr(CO)17] and [Et4N][SbFe3Cr(CO)17] and the ring complex Bi2Fe2(CO)8Me2," Inorg. Chem. 1989, 28, 3164-70.

  146. (146)Whitmire, K. H. In Rings, Clusters and Polymers of Main Group and Transition Elements; Roesky, H. W., Ed.; Elsevier: Amsterdam, 1989, p 503-541.

  147. (147)Scholz, J. N.; Engel, P. S.; Glidewell, C.; Whitmire, K. H. "Reaction of hydroxylamine with benzenesulfonyl chloride. X-ray crystal structure of Piloty's acid and other benzenesulfonylhydroxylamines," Tetrahedron 1989, 45, 7695-708.

  148. (148)Luo, S.; Whitmire, K. H. "Synthesis and characterization of a series of antimonycontaining iron carbonyl complexes: [Et4N]3[SbFe4(CO)16], [Et4N]2[HSbFe4(CO)13], [Et4N][H2SbFe4(CO)13], and [Et4N]2[ClSbFe3(CO)12]," Inorg. Chem. 1989, 28, 1424-31.

  149. (149)Luo, S.; Whitmire, K. H. "Synthesis and structures of two new mixed antimonyiron carbonyl clusters: [R4N][SbFe4(CO)16] (R = Me, Et) and [Et4N]2[Sb2Fe6(CO)20]," J. Organomet. Chem. 1989, 376, 297-310.

  150. (150)Leigh, J. S.; Whitmire, K. H.; Yee, K. A.; Albright, T. A. "Reversible redox processes in main-group/transition-metal clusters: the [Sb2Co4(CO)10(μ-CO)]-/2- couple," J. Am. Chem. Soc. 1989, 111, 2726-7.

  151. (151)Leigh, J. S.; Whitmire, K. H. "The structure of hydridotricarbonyl(tricyclohexylphosphine)cobalt(I)," Acta Cryst. 1989, C45, 210-12.

  152. (152)Ciufolini, M. A.; Hermann, C. W.; Whitmire, K. H.; Byrne, N. E. "Chemoenzymatic preparation of trans-2,6-dialkylpiperidines and of other azacycle building blocks. Total synthesis of (+)-desoxoprosopinine," J. Am. Chem. Soc. 1989, 111, 3473-5.

  153. (153)Cassidy, J. M.; Whitmire, K. H. ""Electron-deficient" trigonal-planar tin- and lead-containing iron carbonyl complexes: [Et4N]2[E{Fe(CO)4}3] (E = Sn, Pb)," Inorg. Chem. 1989, 28, 2494-6.

  154. (154)Whitmire, K. H.; Leigh, J. S.; Luo, S.; Shieh, M.; Fabiano, M. D.; Rheingold, A. L. "The isolation and characterization of organoiron clusters containing four coordinate antimony atoms: [Et4N][Fe3(CO)9(μ-CO){μ3-SbFe(CO)4}] and [Et4N]2[Fe3(CO)93-SbFe(CO)4}2]," New J. Chem. 1988, 12, 397-404.

  155. (155)Whitmire, K. H.; Cassidy, J. M.; Rheingold, A. L.; Ryan, R. R. "A series of thallium-iron carbonyl cluster molecules: structural comparisons of [Et4N]2[Tl2Fe4(CO)16], [Et4N]4[Tl4Fe8(CO)30], and [Et4N]6[Tl6Fe10(CO)36]," Inorg. Chem. 1988, 27, 1347-53.

  156. (156)Whitmire, K. H. "The interface of main group and transition metal cluster chemistry," J. Coord. Chem. 1988, 17, 95-204.

  157. (157)Leigh, J. S.; Whitmire, K. H. "[Cp2Co][Bi[Co(CO)4]4]: a paramagnetic, tetrahedral ten-electron complex of bismuth," Angew. Chem. 1988, 100, 399-400.

  158. (158)Engel, P. S.; Hoque, A. K. M. M.; Scholz, J. N.; Shine, H. J.; Whitmire, K. H. "The reaction of 2,3-diazabicyclo[2.2.2]oct-2-ene with stable cation radical salts," J. Am. Chem. Soc. 1988, 110, 7880-2.

  159. (159)Whitmire, K. H.; Shieh, M.; Lagrone, C. B.; Robinson, B. H.; Churchill, M. R.; Fettinger, J. C.; See, R. F. "Transformations in the bismuth-iron carbonyl cluster system: importance of oxidation/reduction reactions. Crystal structures of tris(tetramethylammonium)tridecacarbonyldibismuthtetraferrate(2-) chloride and tetraethylammonium decacarbonyldibismuthcobaltdiferrate(1-)," Inorg. Chem. 1987, 26, 2798-807.

  160. (160)Whitmire, K. H.; Leigh, J. S.; Gross, M. E. "Isolation and characterization of the strained cluster complex, (μ3-Bi)Co3(CO)6(μ-CO)3; the application of thermogravimetric analysis to rational cluster reactions," J. Chem. Soc., Chem. Comm. 1987, 926-7.

  161. (161)Whitmire, K. H.; Lagrone, C. B.; Churchill, M. R.; Fettinger, J. C.; Robinson, B. H. "Oxidation/reduction chemistry of iron carbonyl clusters containing germanium, tin, or lead: crystal and molecular structures of [Et4N]2[Fe3(CO)93-CO)(μ3-Ge{Fe(CO)4})] and Pb[Fe2(CO)8]2," Inorg. Chem. 1987, 26, 3491-9.

  162. (162)Stanghellini, P. L.; Sailor, M. J.; Kuznesof, P.; Whitmire, K. H.; Hriljac, J. A.; Kolis, J. W.; Zheng, Y.; Shriver, D. F. "Vibrational frequencies associated with the carbide ligand in iron butterfly clusters," Inorg. Chem. 1987, 26, 2950-4.

  163. (163)Rheingold, A. L.; Geib, S. J.; Shieh, M.; Whitmire, K. H. "Synthesis and characterization of a double-spiro μ4-antimony metal carbonyl complex, [Fe2(CO)84-Sb)]2[Fe2(CO)6]," Inorg. Chem. 1987, 26, 463-5.

  164. (164)Whitmire, K. H.; Ryan, R. R.; Wasserman, H. J.; Albright, T. A.; Kang, S. K. "An electron-deficient thallium Zintl-metal carbonylate: structure and bonding of [Et4N]6[Tl6Fe10(CO)36]," J. Am. Chem. Soc. 1986, 108, 6831-2.

  165. (165)Whitmire, K. H.; Raghuveer, K. S.; Churchill, M. R.; Fettinger, J. C.; See, R. F. "Effect of charge on bond formation and cleavage in main-group-transition-metal clusters: the reactions of Bi2Fe3(CO)9 with [Fe(CO)4]2- and [Co(CO)4]-," J. Am. Chem. Soc. 1986, 108, 2778-80.

  166. (166)Whitmire, K. H.; Lee, T. R.; Lewis, E. S. "Kinetics and mechanism of the reaction of [Et4N][HFe(CO)4] and alkyl halides. The unexpected formation of acetone," Organometallics 1986, 5, 987-94.

  167. (167)Whitmire, K. H.; Lagrone, C. B.; Rheingold, A. L. "Lewis basicity of carbonyl oxygen in the presence of a heteroatom: reaction of decacarbonylbismuthtriferrate(1-) with trifluoromethyl methylsulfonate," Inorg. Chem. 1986, 25, 2472-4.

  168. (168)Whitmire, K. H.; Albright, T. A.; Kang, S. K.; Churchill, M. R.; Fettinger, J. C. "Structural and theoretical discussion of tridecacarbonyltetrabismuthtetraferrate(2-): application of MO and Teo electron counting theories to a Zintl-metal carbonylate," Inorg. Chem. 1986, 25, 2799-805.

  169. (169)Lagrone, C. B.; Whitmire, K. H.; Churchill, M. R.; Fettinger, J. C. "Synthesis and characterization of an iron carbonyl cluster containing lead: crystal and molecular structure of [Et4N]2[Pb{Fe(CO)4}2{Fe2(CO)8}]," Inorg. Chem. 1986, 25, 2080-5.

  170. (170)Churchill, M. R.; Fettinger, J. C.; Whitmire, K. H.; Lagrone, C. B. "X-ray structural characterization of [Et4N+]3[BiFe4(CO)163-]," J. Organomet. Chem. 1986, 303, 99-109.

  171. (171)Chang, S. C.; Kafafi, Z. H.; Hauge, R. H.; Whitmire, K. H.; Billups, W. E.; Margrave, J. L. "Infrared spectrum of hexacarbonylbis(μ-carbonyl)(μ-methylene)diiron, Fe2(CO)6(μ-CO)2(μ-CH2), in cryogenic matrixes," Inorg. Chem. 1986, 25, 4530-3.

  172. (172)Whitmire, K. H.; Lee, T. R. "Carbon-13 NMR studies of some iron carbonyls: an unexpected trend in the chemical shifts of disubstituted complexes," J. Organomet. Chem. 1985, 282, 95-106.

  173. (173)Whitmire, K. H.; Churchill, M. R.; Fettinger, J. C. "Synthesis and crystal structure of the bismuth-iron carbonyl cluster [Et4N]2[Bi4Fe4(CO)13]. Discovery of a hybrid Zintl-metal carbonyl cluster," J. Am. Chem. Soc. 1985, 107, 1056-7.

  174. (174)Churchill, M. R.; Fettinger, J. C.; Whitmire, K. H. "Synthesis and x-ray crystallographic characterization of (μ3-Bi)2Fe3(CO)9: a reformulation of Hieber's Bi2Fe5(CO)20," J. Organomet. Chem. 1985, 284, 13-23.

  175. (175)Whitmire, K. H.; Lagrone, C. B.; Churchill, M. R.; Fettinger, J. C.; Biondi, L. V. "Synthesis and characterization of an iron carbonyl cluster containing bismuth: crystal and molecular structure of tetraethylammonium (μ3- bismuthido)nonacarbonyl(m3-carbonyl)-triangulo-triferrate(1-), [Et4N][(μ3-Bi)Fe3(CO)93-CO)], a closo cluster of the first transition series with a large heteroatom," Inorg. Chem. 1984, 23, 4227-32.

  176. (176)Johnson, B. F. G.; Lewis, J.; Raithby, P. R.; Azman, S. N.; Syed-Mustaffa, B.; Taylor, M. J.; Whitmire, K. H.; Clegg, W. "Synthesis of mixed-metal clusters by the reaction of the unsaturated cluster decacarbonylbis(m-hydrido)triosmium with transition metal hydrides: the x-ray crystal structures of [Os3H3(CO)10[Cu(PPh3)]] and [Os3H3(CO)11[Ir(PPh3)]]," J. Chem. Soc., Dalton Trans. 1984, 2111-18.

  177. (177)Bogdan, P. L.; Whitmire, K. H.; Kolis, J. W.; Shriver, D. F.; Holt, E. M. "Protonation and protolysis of [Fe4(CO)12(CCH3)]," J. Organomet. Chem. 1984, 272, 169-77.

  178. (178)Johnson, B. F. G.; Lewis, J.; Nicholls, J. N.; Puga, J.; Whitmire, K. H. "Formation of new halo mixed-metal clusters by oxidative addition of triphenylphosphinegold(I) halides to carbidopentadecacarbonylpentaruthenium: crystal and molecular structures of [Ru5C(CO)15{μ-Au(PPh3)}Cl] and [Ru5C(CO)14{μ-Au(PPh3)}(μ-Br)]," J. Chem. Soc., Dalton Trans. 1983, 787-97.

  179. (179)Johnson, B. F. G.; Lewis, J.; Nelson, W. J. H.; Puga, J.; Raithby, P. R.; Whitmire, K. H. "Synthesis, reactivity, and x-ray crystal structure of the cationic cluster complex bis(acetonitrile)trihydridotetrakis[tricarbonylosmium(I)] tetrafluoroborate," J. Chem. Soc., Dalton Trans. 1983, 1339-44.

  180. (180)Goudsmit, R. J.; Johnson, B. F. G.; Lewis, J.; Raithby, P. R.; Whitmire, K. H. "Synthesis, reactivity, and molecular structure of the raft complex [Os63-O)(μ3-CO)(CO)18]," J. Chem. Soc., Chem. Comm. 1983, 246-7.

  181. (181)Whitmire, K. H., 1982.

  182. (182)Whitmire, K.; Ross, J.; Cooper, C. B., III; Shriver, D. F. "Bis[m-nitridobis(triphenylphosphorus)(+)] tridecacarbonyltetraferrate(2-) or [bis(triphenylphosphine)iminium tridecacarbonyltetraferrate](2-) [PPN]2[Fe4(CO)13]," Inorg. Synth. 1982, 21, 66-9.

  183. (183)Kolis, J. W.; Holt, E. M.; Drezdzon, M.; Whitmire, K. H.; Shriver, D. F. "A reactive three-metal carbide cluster precursor, [Fe3(CO)9(CCO)]2-," J. Am. Chem. Soc. 1982, 104, 6134-5.

  184. (184)Johnson, B. F. G.; Lewis, J.; Nelson, W. J. H.; Puga, J.; Raithby, P. R.; Schroder, M.; Whitmire, K. H. "Synthesis and x-ray crystal structure of the cluster cation [Os42-H)3(CO)12(NCMe)2]+: an example of an unsupported butterfly tetraosmium geometry," J. Chem. Soc., Chem. Comm. 1982, 610-12.

  185. (185)Holt, E. M.; Whitmire, K. H.; Shriver, D. F. "Nucleophilic attack and structural rearrangements in some iron carbonyl cluster carbides. Syntheses, structures, and reactions of the tetrahedral four-iron clusters [Fe4(CO)123-COMe)]- and [Fe4(CO)12(CMe)]," J. Am. Chem. Soc. 1982, 104, 5621-6.

  186. (186)Goudsmit, R. J.; Johnson, B. F. G.; Lewis, J.; Raithby, P. R.; Whitmire, K. H. "Synthesis and x-ray crystal structure of the cluster [Os6(CO)17[P(OMe)3]4], an example of a hexa-metal planar complex," J. Chem. Soc., Chem. Comm. 1982, 640-2.

  187. (187)Drezdzon, M. A.; Whitmire, K. H.; Bhattacharyya, A. A.; Hsu, W. L.; Nagel, C. C.; Shore, S. G.; Shriver, D. F. "Proton-induced reduction of CO to CH4 in homonuclear and heteronuclear metal carbonyls: a survey of the influence of the metal and nuclearity," J. Am. Chem. Soc. 1982, 104, 5630-3.

  188. (188)Braga, D.; Johnson, B. F. G.; Lewis, J.; Mace, J. M.; McPartlin, M.; Puga, J.; Nelson, W. J. H.; Raithby, P. R.; Whitmire, K. H. "The reaction of nitrosyl cation with some anions of osmium and ruthenium: synthesis and x-ray characterization of [H3Os4(CO)122-NO)] and [HRu4N(CO)11P(OMe)3]," J. Chem. Soc., Chem. Comm. 1982, 1081-3.

  189. (189)Whitmire, K. H.; Shriver, D. F. "(μ-H)Fe4(CO)122-COH): evidence for a protonated η2-CO complex as an intermediate in the proton-induced reduction of carbon monoxide," J. Am. Chem. Soc. 1981, 103, 6754-5.

  190. (190)Holt, E. M.; Whitmire, K. H.; Shriver, D. F. "The role of metal cluster interactions in the proton-induced reduction of carbonyl. The crystal structures of [PPN][HFe4(CO)12C] and HFe4(CO)122-COCH3)," J. Organomet. Chem. 1981, 213, 125-37.

  191. (191)Whitmire, K.; Shriver, D. F.; Holt, E. M. "Structural and isotope tracer study of the proton induced reduction of carbonyl in [Fe4(CO)11(μ-CO)(μ3-COMe)]-; x-ray crystal structure of [Fe4H(CO)12COMe]," J. Chem. Soc., Chem. Comm. 1980, 780-1.

  192. (192)Whitmire, K.; Shriver, D. F. "A new reaction for the conversion of carbon monoxide into methane: proton-induced reduction of carbon monoxide in a metal carbonyl cluster, [Fe4(CO)132-]," J. Am. Chem. Soc. 1980, 102, 1456-7.

  193. (193)Holt, E. M.; Whitmire, K.; Shriver, D. F. "O-Alkylation and structural rearrangement of carbonyl ligands in [Fe4(CO)9(μ-CO)33-CO)]2-; x-ray crystal structure of [N(PPh3)2][Fe4(CO)11(μ-CO)(μ3-COMe)]," J. Chem. Soc., Chem. Comm. 1980, 778-9.

  194. (194)Strauss, S. H.; Whitmire, K. H.; Shriver, D. F. "Rhodium(I)-catalyzed decomposition of formic acid," J. Organomet. Chem. 1979, 174, C59-C62.

  195. (195)Huddle, B. P.; Whitmire, K. "An improved Victor-Meyer apparatus," J. Chem. Ed. 1977, 54, 261.